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JP7587142B2 - Sinter manufacturing method - Google Patents
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JP7587142B2 - Sinter manufacturing method - Google Patents

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JP7587142B2
JP7587142B2 JP2021028678A JP2021028678A JP7587142B2 JP 7587142 B2 JP7587142 B2 JP 7587142B2 JP 2021028678 A JP2021028678 A JP 2021028678A JP 2021028678 A JP2021028678 A JP 2021028678A JP 7587142 B2 JP7587142 B2 JP 7587142B2
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泰英 山口
愛華 浜田
茜 石田
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Description

本発明は、焼結鉱の製造において、微粉原料を造粒する方法に関する。特に、分割造粒法を用いて微粉原料を造粒する方法に関する。 The present invention relates to a method for granulating fine raw materials in the production of sintered ore. In particular, the present invention relates to a method for granulating fine raw materials using a separate granulation method.

近年、鉄鉱石の資源枯渇化・劣質化に伴い、鉄鉱石の脈石成分(SiO・Al)が増加している。その為、選鉱処理にて人工的に高Fe品位にした微粉鉱石(精鉱、ペレットフィード(PF)とも言う)の使用量を増加させ、鉄鉱石中の脈石成分(SiO・Al)を維持・低下していくことが焼結鉱の製造において今後重要となる。 In recent years, the amount of gangue components ( SiO2 · Al2O3 ) in iron ore has increased due to the depletion and deterioration of iron ore resources. Therefore, it will be important in the future to increase the amount of fine ore (also called concentrate or pellet feed ( PF)) that has been artificially treated to have a high Fe content in the ore dressing process and maintain or reduce the gangue components ( SiO2 · Al2O3 ) in iron ore in the production of sintered ore.

そこで微粉鉱石を選択・分割造粒設備で造粒することによって、直径5~15mmの粗大造粒物にし、それらを従来の本造粒設備で処理した原料と共に焼結機に充填することで未造粒粉を削減し、微粉鉱石による原料充填層の通気性悪化および生産性低下を回避する技術開発が進められている[非特許文献1]。 Therefore, technological development is being carried out to granulate fine ore using selective and separate granulation equipment to produce coarse granules with diameters of 5 to 15 mm, which are then charged into a sintering machine together with raw materials processed using conventional granulation equipment to reduce the amount of ungranulated powder, and to avoid the deterioration of the air permeability of the raw material packed bed caused by the fine ore and the drop in productivity [Non-Patent Document 1].

ここに、微粉鉱石の種類として、ヘマタイト系(Fe)微粉鉱石とマグネタイト系(Fe(FeO・Fe))微粉鉱石が知られている。特許文献1には、特に、マグネタイト系微粉鉱石を単独使用する方法が開示されている。 Known types of fine ore include hematite (Fe 2 O 3 ) fine ore and magnetite (Fe 3 O 4 (FeO.Fe 2 O 3 )) fine ore. Patent Document 1 discloses a method of using magnetite fine ore alone.

また、非特許文献2においても、マグネタイト系微粉鉱石は、CaOの添加なしでも、CaOを添加したヘマタイト系微粉鉱石と同等の焼成後強度が得られたとの知見も示されている。
さらに、特許文献2には、ヘマタイト系微粉鉱石の造粒に際して、微粉鉱石に対して核となる粉鉱石を1.5/1以上3/1未満の比(微粉鉱石/粉鉱石)で添加することで造粒物の強度が向上することが示されている。
Also, Non-Patent Document 2 indicates the finding that magnetite-based fine ore, even without the addition of CaO, has a post-sintering strength equivalent to that of hematite-based fine ore to which CaO is added.
Furthermore, Patent Document 2 shows that when granulating hematite-based fine ore, the strength of the granulated product is improved by adding fine ore as nuclei to the fine ore in a ratio (fine ore/fine ore) of 1.5/1 or more and less than 3/1.

特開2013-253281号公報JP 2013-253281 A 特開2016-191122号公報JP 2016-191122 A

T. K. Sandeep et al:Metallurgical and Materials Transaction B, Volume 46B, N o 2(2015), 635T. K. Sandeep et al: Metallurgical and Materials Transaction B, Volume 46B, No 2 (2015), 635 T. K. Sandeep et al.:Metallurgical and Materials Transaction B, Volume 47B, N o 1(2016), 309T. K. Sandeep et al. :Metallurgical and Materials Transaction B, Volume 47B, No. 1 (2016), 309

詳細は後述するが、マグネタイト系微粉鉱石を多く用いた場合、例えば焼結鉱の強度が高まる。このため、マグネタイト系微粉鉱石をなるべく多く使用して焼結鉱を製造したいという要望が強くなってきている。しかしながら、マグネタイト系微粉鉱石は、鉱山の近く、あるいは出荷港に併設されたペレット工場でペレットまで加工されてから出荷される例が非常に多い。このため、マグネタイト系微粉鉱石が鉄鉱石の海上貿易市場に流通している量は現状少ない。そのため、特許文献1記載の方法のように、ヘマタイト系微粉鉱石を使用せず、焼結鉱の原料となる鉄鉱石の全量をマグネタイト系微粉鉱石とすることは実現性が低い。また、ヘマタイト系微粉鉱石とマグネタイト系微粉鉱石とを併用する検討はこれまでなされていない。特許文献2記載の方法では、粉鉱石を核として添加することが検討されているものの、このような粉鉱石を核としつつ、更にヘマタイト系微粉鉱石とマグネタイト系微粉鉱石とを併用する検討もこれまで存在しない。 As will be described in detail later, when a large amount of magnetite-based fine ore is used, for example, the strength of sintered ore increases. For this reason, there is a growing demand to produce sintered ore using as much magnetite-based fine ore as possible. However, magnetite-based fine ore is often processed into pellets at a pellet factory near the mine or at the shipping port before being shipped. For this reason, the amount of magnetite-based fine ore currently circulating in the iron ore sea trade market is small. Therefore, as in the method described in Patent Document 1, it is not feasible to use magnetite-based fine ore as the entire amount of iron ore used as the raw material for sintered ore without using hematite-based fine ore. In addition, there has been no study to date on the use of hematite-based fine ore and magnetite-based fine ore in combination. In the method described in Patent Document 2, the addition of fine ore as a nucleus is considered, but there has been no study to date on the use of hematite-based fine ore and magnetite-based fine ore in combination while using such fine ore as a nucleus.

本発明の目的は、焼成後の焼結鉱の強度の低下を抑制しつつ、マグネタイト系微粉鉱石を購入容易なヘマタイト系微粉鉱石に置換することが可能な焼結鉱の製造方法を提供することである。すなわち、マグネタイト系微粉鉱石の一部をヘマタイト系微粉鉱石で置換した造粒物が、焼結鉱製造時のハンドリング性や焼成後の焼結鉱強度において、マグネタイト系微粉鉱石のみの造粒物と同等となる置換範囲を明らかとする。 The object of the present invention is to provide a method for producing sintered ore that can replace magnetite-based fine ore with easily purchased hematite-based fine ore while suppressing a decrease in the strength of the sintered ore after firing. In other words, the present invention clarifies the range of substitution in which a granulated material in which a portion of magnetite-based fine ore has been replaced with hematite-based fine ore is equivalent to a granulated material made only of magnetite-based fine ore in terms of handleability during sintered ore production and sintered ore strength after firing.

本発明者は、まず、電気炉を用いた基礎的な実験を行い、マグネタイト系微粉鉱石とヘマタイト系微粉鉱石との混合物の焼成後の強度を測定した。そして、本発明者は、混合物中のマグネタイト系微粉鉱石の混合率が50質量%以上あれば、混合物の焼成体がマグネタイト系微粉鉱石単独の焼成体と同等の強度を呈することを明らかとした。次に、本発明者は、実用的な原料配合条件で焼結実験を行った。この結果、本発明者は、焼結鉱の強度においても、ヘマタイト系微粉鉱石とマグネタイト系微粉鉱石の総質量に対するマグネタイト系微粉鉱石の混合率を前記範囲とすることで、マグネタイト系微粉鉱石単独の場合(すなわち、鉄含有原料の微粉鉱石としてマグネタイト系微粉鉱石のみを使用した場合)と同等の強度が得られることを確認した。
本発明は、かかる検討結果に基づいて考案されたもので、その要旨は以下である。
The inventor first conducted a basic experiment using an electric furnace to measure the strength of a mixture of magnetite-based fine ore and hematite-based fine ore after sintering. The inventor then clarified that if the mixture contains magnetite-based fine ore at a mixing ratio of 50% by mass or more, the sintered product of the mixture exhibits a strength equivalent to that of a sintered product containing only magnetite-based fine ore. Next, the inventor conducted a sintering experiment under practical raw material blending conditions. As a result, the inventor confirmed that the strength of the sintered ore can be obtained by setting the mixing ratio of magnetite-based fine ore to the total mass of hematite-based fine ore and magnetite-based fine ore within the above range, as well as the strength of the sintered ore, which is equivalent to that of the magnetite-based fine ore alone (i.e., the magnetite-based fine ore alone is used as the fine ore of the iron-containing raw material).
The present invention was devised based on the results of such investigations, and the gist of the present invention is as follows.

本発明の要旨とするところは、以下である。
本発明のある観点によれば、焼結原料を、主焼結原料と、微粉鉱石を含む副焼結原料とに分け、前記主焼結原料を混合及び造粒する主造粒工程と、前記副焼結原料を混合及び造粒する副造粒工程とを並列で行い、前記主造粒工程と前記副造粒工程で製造したそれぞれの造粒物を合わせ、前記合わせた造粒物を焼成して焼結鉱を製造する焼結鉱の製造方法であって、前記副造粒工程に用いられる前記微粉鉱石がマグネタイト系微粉鉱石とヘマタイト系微粉鉱石の混合物であって、前記マグネタイト系微粉鉱石の、前記マグネタイト系微粉鉱石と前記ヘマタイト系微粉鉱石との総質量に対する混合率が50質量%以上100質量%未満であることを特徴とする微粉原料の造粒方法が提供される。
ここに、前記マグネタイト系微粉鉱石の粒度は、前記ヘマタイト系微粉鉱石の粒度以下であることが好ましい。
さらに、前記副焼結原料がさらに粉鉱石を含み、前記微粉鉱石と前記粉鉱石の質量比が1.5/1以上3/1未満であることが好ましい。
The gist of the present invention is as follows.
According to one aspect of the present invention, there is provided a method for producing sintered ore, which comprises: dividing a sintering raw material into a main sintering raw material and a sub-sintering raw material containing fine ore; performing a main granulation process for mixing and granulating the main sintering raw material in parallel with a sub-granulation process for mixing and granulating the sub-sintering raw material; combining the granulated products produced in the main granulation process and the sub-granulation process; and firing the combined granulated product to produce sintered ore. The fine ore used in the sub-granulation process is a mixture of magnetite-based fine ore and hematite-based fine ore, and the mixing ratio of the magnetite-based fine ore to the total mass of the magnetite-based fine ore and the hematite-based fine ore is 50% by mass or more and less than 100% by mass.
Here, the particle size of the magnetite-based fine ore is preferably equal to or smaller than the particle size of the hematite-based fine ore.
Furthermore, it is preferable that the auxiliary sintering raw material further contains fine ore, and the mass ratio of the fine ore to the fine ore is 1.5/1 or more and less than 3/1.

焼成後の焼結鉱の強度の低下を抑制しつつ、マグネタイト系微粉鉱石をヘマタイト系微粉鉱石に置換できる。 Magnetite-based fine ore can be replaced with hematite-based fine ore while preventing a decrease in the strength of the sintered ore after firing.

電気炉を用いた基礎的な実験に用いた装置の模式図である。FIG. 1 is a schematic diagram of an apparatus used in a basic experiment using an electric furnace. マグネタイト系微粉鉱石の混合率(質量%)と落錘後平均粒度(mm)の関係を示す図である。FIG. 1 is a diagram showing the relationship between the mixing ratio (mass%) of magnetite-based fine ore and the average particle size (mm) after dropping. 造粒処理系統のフロー(造粒装置)を模式的に示す図である。FIG. 2 is a diagram showing a schematic flow of a granulation processing system (granulation device). 焼結実験(鍋試験)に用いた装置の構成を模式的に示す図である。FIG. 2 is a diagram showing a schematic configuration of an apparatus used in a sintering experiment (pot test).

以下に添付図面を参照しながら、本発明の好適な実施の形態について詳細に説明する。なお、本実施形態で使用される各原料は多数の粒子の集合体となっている。特に断りがない限り、各原料の原料名はその原料を構成する粒子の集合体を意味するものとする。また、「~」を用いて表される数値限定範囲は、「~」の前後に記載される数値を下限値及び上限値として含む範囲を意味する。「超」または「未満」と示す数値は、その値が数値範囲に含まれない。 A preferred embodiment of the present invention will be described in detail below with reference to the attached drawings. Each raw material used in this embodiment is an aggregate of many particles. Unless otherwise specified, the name of each raw material refers to the aggregate of particles that make up that raw material. A numerical range expressed using "~" refers to a range that includes the numerical values written before and after "~" as the lower and upper limits. Numerical values indicated as "greater than" or "less than" are not included in the numerical range.

<本発明に至った基礎的検討>
ヘマタイト系微粉鉱石にマグネタイト系微粉鉱石を混合した場合、ヘマタイト系微粉鉱石とマグネタイト系微粉鉱石の性質の違いにより、マグネタイト系微粉鉱石の混合率によって強度が変化すると考えられる。そこで、ヘマタイト系微粉鉱石にマグネタイト系微粉鉱石を混合していった場合の強度変化を実験的に調査した。
<Basic studies leading to the present invention>
When hematite fine ore is mixed with magnetite fine ore, it is considered that the strength changes depending on the mixing ratio of magnetite fine ore due to the difference in the properties of hematite fine ore and magnetite fine ore. Therefore, the change in strength when hematite fine ore is mixed with magnetite fine ore was experimentally investigated.

(実験方法および実験条件)
ヘマタイト系微粉鉱石(本実験においてHと称する場合がある)とマグネタイト系微粉鉱石(本実験においてMと称する場合がある)を供試料とした(表1)。マグネタイト系微粉鉱石の混合率および粒度の組合せの影響をそれぞれ検討するにあたり、各鉱石を20~45μmと63~125μmに篩分級した。ここに、篩分級による粒度範囲において、「A~Bμm」は、目開きA(μm)の篩に残り、目開きB(μm)の篩から落ちた鉱石の粒度範囲を示す。篩分級における「A~Bμm」はA以上B未満を示す。以降はヘマタイト系微粉鉱石の20~45μmをH細、63~125μmをH粗、同様にマグネタイト系微粉鉱石の20~45μmをM細、63~125μmをM粗、とも称する。なお、表1にはH細、H粗、M細、M粗の組成も示した。当該組成は化学分析により特定した。
(Experimental Method and Conditions)
Hematite-based fine ore (sometimes referred to as H in this experiment) and magnetite-based fine ore (sometimes referred to as M in this experiment) were used as samples (Table 1). In order to examine the effects of the mixing ratio and particle size combination of magnetite-based fine ore, each ore was sieved into 20-45 μm and 63-125 μm. Here, in the particle size range by sieve classification, "A-B μm" indicates the particle size range of the ore that remains on the sieve with mesh size A (μm) and falls through the sieve with mesh size B (μm). In sieve classification, "A-B μm" indicates A or more and less than B. Hereinafter, hematite fine ore with a size of 20 to 45 μm will be referred to as H-fine, and 63 to 125 μm as H-coarse. Similarly, magnetite fine ore with a size of 20 to 45 μm will be referred to as M-fine, and 63 to 125 μm as M-coarse. Table 1 also shows the compositions of H-fine, H-coarse, M-fine, and M-coarse. The compositions were determined by chemical analysis.

鉱石種2水準、粒度2水準の4水準の組合せ条件で各々混合率を7から9水準変更することで、合計29水準の試料を作製した。そして、これらの試料を用いてマグネタイト系微粉鉱石の混合率および粒度の組合せの影響をそれぞれ検討した。 A total of 29 samples were prepared by changing the mixing ratio by 7 to 9 levels under four combination conditions (two levels of ore type and two levels of particle size). These samples were then used to examine the effects of the mixing ratio and particle size combination of magnetite-based fine ore.

具体的には、まず、2種類(H細、H粗、M細、M粗のいずれか2種類)の微粉鉱石を所定の混合率で混合した混合物約1.6gに水分を約3.6%分添加し、ダイスに充填して4.8MPaの圧力を30秒間加えた。これにより、直径8mm、高さ約10mmの円柱状タブレットを成型した。 Specifically, first, about 3.6% water was added to about 1.6 g of a mixture of two types of fine ore (two types from among H fine, H coarse, M fine, and M coarse) mixed at a specified mixing ratio, and the mixture was filled into a die and subjected to a pressure of 4.8 MPa for 30 seconds. This produced a cylindrical tablet with a diameter of 8 mm and a height of about 10 mm.

Figure 0007587142000001
Figure 0007587142000001

ついで、成型したタブレットを電気炉にて、実機の焼結機を模擬したヒートパターン(昇温速度200℃/min、最高到達温度1300℃、最高温度保持時間0秒、降温速度67℃/min)で焼成した。焼成に用いた装置を図1に模式的に示す。焼成後のタブレットに300gの荷重を30cmの高さから3回落とす落錘試験を行った。落錘試験後、試料の篩分けを行い、平均粒度(平均粒径)を算出し強度を評価した。(以降これを落錘後平均粒度と称する。)具体的には、目開き4.75mm、2.8mm、2.0mm、1.0mm、0.5mm、0.25mm、0.125mmの篩を重ねて篩分けを行い、それぞれの篩目と一つ上の篩目の平均値を代表粒径(例えば2.0~2.8mmの場合2.4mm)とし、代表粒径と重量比の積の総和にて加重平均値を算出した。実焼結鉱の強度面から、落錘後平均粒度は1.5mm以上であることが、局所的な脆弱部を形成せずに最低限の焼結鉱強度を確保する観点より必要と考えられる。落錘後平均粒度が2.5mm以上であると十分に高い強度が得られる為により好ましい。 The molded tablets were then fired in an electric furnace with a heat pattern simulating that of an actual sintering machine (heating rate 200°C/min, maximum temperature reached 1300°C, maximum temperature holding time 0 seconds, cooling rate 67°C/min). The equipment used for firing is shown diagrammatically in Figure 1. A drop weight test was conducted in which a 300g load was dropped from a height of 30cm three times on the fired tablets. After the drop weight test, the samples were sieved to calculate the average particle size (average particle size) and evaluate the strength. (Hereinafter, this will be referred to as the average particle size after dropping.) Specifically, sieves with mesh sizes of 4.75 mm, 2.8 mm, 2.0 mm, 1.0 mm, 0.5 mm, 0.25 mm, and 0.125 mm were stacked to perform sieving, and the average value of each sieve and the next higher sieve was taken as the representative particle size (for example, 2.4 mm for 2.0 to 2.8 mm), and the weighted average value was calculated as the sum of the products of the representative particle size and the weight ratio. From the perspective of the strength of the actual sintered ore, it is considered necessary for the average particle size after dropping to be 1.5 mm or more in order to ensure the minimum sintered ore strength without forming localized weak parts. It is more preferable for the average particle size after dropping to be 2.5 mm or more, as this will provide sufficiently high strength.

各水準でタブレットを4個焼成し、3個を落錘試験、1個を樹脂に埋め込んで研磨し断面組織観察および画像解析に供した。また、マグネタイト系微粉鉱石の混合率が25質量%、50質量%、75質量%のタブレットは各1個成型まで行い、その後焼成せずに樹脂に埋め込んで研磨し断面組織観察および画像解析に供した。 Four tablets of each level were fired, three were subjected to a drop weight test, and one was embedded in resin and polished for cross-sectional structure observation and image analysis. In addition, one tablet each with a mixing ratio of magnetite-based fine powder ore of 25 mass%, 50 mass%, and 75 mass% was molded, and then embedded in resin without firing, polished, and subjected to cross-sectional structure observation and image analysis.

(実験結果)
落錘後平均粒度の変化を図2に示す。粒度組合せが異なるいずれの条件においても、マグネタイト系微粉鉱石(ここではM細またはM粗)の混合率の上昇に伴い、落錘後平均粒度、すなわち焼成後の強度は上昇した。しかし強度の上昇量は一定ではなく、マグネタイト系微粉鉱石の混合率が25質量%未満ではほとんど上昇せず、25~50質量%で特に大きく上昇し、50質量%以降は傾きが再び緩やかになり、混合率75質量%~80質量%にてマグネタイト系微粉鉱石単独(100%)の強度値と概ね同等になることが判明した。また、M細を含む組合せにおいて、タブレットがより高強度となることが判明した。
(Experimental Results)
The change in the average particle size after the weight drop is shown in Figure 2. Under all different particle size combination conditions, the average particle size after the weight drop, i.e., the strength after firing, increased with an increase in the mixing ratio of magnetite-based fine ore (here, M fine or M coarse). However, the increase in strength was not constant; when the mixing ratio of magnetite-based fine ore was less than 25 mass%, there was almost no increase, and when the mixing ratio was 25 to 50 mass%, the increase was particularly large, and after 50 mass%, the slope became gentle again, and when the mixing ratio was 75 mass% to 80 mass%, the strength value was roughly equivalent to that of magnetite-based fine ore alone (100%). It was also found that the tablet had a higher strength in the combination containing M fine.

(作用)
マグネタイト系微粉鉱石とヘマタイト系微粉鉱石の造粒物の結合の機構として、(1)マグネタイト粒子同士の結合、(2)マグネタイト粒子とヘマタイト粒子の結合、(3)ヘマタイト粒子同士の結合の3つがある。このうち、(1)は(2)、(3)に比較して結合強度が大きい。これは、マグネタイト粒子が焼結反応に伴う温度上昇により酸化されてヘマタイト粒子へと変化し、その際の結晶構造や体積の変化によって粒子間の拡散結合が促進される為であると考えられる。従って、マグネタイト系微粉鉱石の増配によって強度が向上する。
(Action)
There are three bonding mechanisms for the granulated product of magnetite-based fine ore and hematite-based fine ore: (1) bonding between magnetite particles, (2) bonding between magnetite particles and hematite particles, and (3) bonding between hematite particles. Of these, (1) has a stronger bonding strength than (2) and (3). This is thought to be because magnetite particles are oxidized by the temperature rise accompanying the sintering reaction and change into hematite particles, and the changes in crystal structure and volume at that time promote diffusion bonding between particles. Therefore, the strength is improved by increasing the amount of magnetite-based fine ore.

また、マグネタイト系微粉鉱石の混合率が50質量%以上となると、(1)の結合が造粒物全体にわたるネットワークを形成するようになる。一旦、この全体にわたるネットワークが形成されるとそれ以降の強度向上は緩やかとなる。従って、マグネタイト系微粉鉱石の混合率が50質量%以上となる場合に、タブレットの強度がマグネタイト系微粉鉱石単独で製造されたタブレットの強度の値に概ね等しくなる。 Furthermore, when the mixing ratio of magnetite-based fine ore is 50% by mass or more, the bonds in (1) form a network throughout the entire granulated material. Once this network is formed throughout the entire granulated material, the strength improvement thereafter becomes gradual. Therefore, when the mixing ratio of magnetite-based fine ore is 50% by mass or more, the strength of the tablet becomes roughly equal to the strength value of a tablet made from magnetite-based fine ore alone.

ここに、粒度の異なる原料の組合せは、ネットワーク形成に影響すると考えられる。H粗とM細の組合せの場合は、ヘマタイト粒子の周囲および粒子間空隙を、細粒のマグネタイト粒子が充填することで、結合強度の大きい(1)のネットワークがH細とM細の組合せと同様に容易に形成される。一方H細とM粗の組合せの場合は、マグネタイト粒子周囲および粒子間空隙を、結合強度が弱い細粒のヘマタイト粒子が充填するので、結合強度の大きい(1)のネットワーク形成が阻害される。
H粗とM粗の組合せの場合、粒子数ひいては粒子同士の接点数自体が少ないため、強度も低い。ただし、いずれの粒度の組み合わせにおいても、マグネタイト系微粉鉱石の混合率が50質量%以上であれば、落錘後平均粒度が1.5mm以上となっている。
Here, it is considered that the combination of raw materials with different particle sizes affects the network formation. In the case of the combination of H coarse and M fine, the fine magnetite particles fill the periphery of the hematite particles and the gaps between the particles, and the network of (1) with high bonding strength is easily formed as in the combination of H fine and M fine. On the other hand, in the case of the combination of H fine and M coarse, the fine hematite particles with weak bonding strength fill the periphery of the magnetite particles and the gaps between the particles, and the network of (1) with high bonding strength is inhibited.
In the case of the combination of H coarse and M coarse, the number of particles and therefore the number of contact points between the particles are small, so the strength is also low. However, in any combination of particle sizes, if the mixing ratio of magnetite fine ore is 50 mass% or more, the average particle size after dropping is 1.5 mm or more.

<実施の態様>
本発明は、前述の基礎的検討に基づいて考案されたもので、微粉原料を選択的に造粒強化する副造粒工程を有する焼結鉱の製造方法であって、前記微粉原料がヘマタイト系微粉鉱石とマグネタイト系微粉鉱石の混合物であり、マグネタイト系微粉鉱石の両者の総質量に対する混合率が50質量%以上100質量%未満であることを特徴とする。
以下、本発明の実施形態を図面に基づいて詳細に説明する。
<Embodiments>
The present invention has been devised based on the above-mentioned fundamental studies, and is a method for producing sintered ore having a secondary granulation process for selectively strengthening the granulation of fine raw materials, characterized in that the fine raw materials are a mixture of hematite-based fine ore and magnetite-based fine ore, and the mixing ratio of the magnetite-based fine ore to the total mass of both is 50 mass% or more and less than 100 mass%.
Hereinafter, an embodiment of the present invention will be described in detail with reference to the drawings.

(全体構成)
図3に本実施形態における造粒処理系統のフローを示す。この造粒処理は、いわゆる選択造粒法あるいは分割造粒法と呼ばれる原料処理方法である。図3に示すように、本造粒処理は、焼結原料を主焼結原料群11と、副焼結原料群21とに分け、それぞれを混合及び造粒する。具体的には、本造粒処理では、主焼結原料群11を造粒する主造粒工程1と、副焼結原料群21を造粒する副造粒工程2とを並列で行う。その後、主造粒工程1と副造粒工程2で製造したそれぞれの造粒物3を合わせ、合わせた造粒物3を焼結機4で焼成する。
(Overall composition)
Fig. 3 shows the flow of the granulation process system in this embodiment. This granulation process is a raw material processing method known as selective granulation or divided granulation. As shown in Fig. 3, in this granulation process, the sintering raw material is divided into a main sintering raw material group 11 and a sub-sintering raw material group 21, and these are mixed and granulated. Specifically, in this granulation process, a main granulation process 1 for granulating the main sintering raw material group 11 and a sub-granulation process 2 for granulating the sub-sintering raw material group 21 are performed in parallel. After that, the granulated products 3 produced in the main granulation process 1 and the sub-granulation process 2 are combined, and the combined granulated products 3 are fired in a sintering machine 4.

(主造粒工程)
主造粒工程1では、所定量の主焼結原料群11をホッパ111からコンベア112に供給し、コンベア112上で主焼結原料群11が配合される。コンベア112は、主焼結原料群11の配合原料をドラムミキサー12に供給する。そして、主焼結原料11の配合原料をドラムミキサー12で混合及び造粒することによって擬似粒子の造粒物13を製造する。主焼結原料群11は、鉄含有原料、副原料、返鉱、ダスト及び炭材を含む。主焼結原料群11は、後述の副焼結原料群21として選択された原料を除いた残りの原料となる。
(Main granulation process)
In the main granulation process 1, a predetermined amount of the main sintering raw material group 11 is supplied from a hopper 111 to a conveyor 112, and the main sintering raw material group 11 is blended on the conveyor 112. The conveyor 112 supplies the blended raw materials of the main sintering raw material group 11 to a drum mixer 12. The blended raw materials of the main sintering raw material 11 are mixed and granulated in the drum mixer 12 to produce granulated products 13 of pseudo particles. The main sintering raw material group 11 includes an iron-containing raw material, an auxiliary raw material, return ore, dust, and carbonaceous material. The main sintering raw material group 11 is the remaining raw materials excluding the raw materials selected as the auxiliary sintering raw material group 21 described below.

図3では連結タンデム型のドラムミキサーを配置しているが、複数のドラムミキサーを直列に配置してもよいし、一つのドラムミキサーによる混合及び造粒を行ってもよい。 In Figure 3, a connected tandem type drum mixer is arranged, but multiple drum mixers may be arranged in series, or mixing and granulation may be performed using a single drum mixer.

(副造粒工程)
副造粒工程2では、所定量の副焼結原料群21をホッパ2111からコンベア2112に供給し、コンベア2112上で副焼結原料群21が配合される。コンベア2112は、副焼結原料群21の配合原料を造粒機に供給する。そして、造粒機で副焼結原料11の配合原料を混合及び造粒して擬似粒子の造粒物24を製造する。造粒機は、例えば、高速撹拌ミキサー22と皿型ペレタイザー23をこの順で組み合わせて配置するのがよい。前者は混合撹拌機能が、後者は造粒機能が高い装置であれば、上記の例に限らない。
(Secondary granulation process)
In the secondary granulation process 2, a predetermined amount of the secondary sintering raw material group 21 is supplied from a hopper 2111 to a conveyor 2112, and the secondary sintering raw material group 21 is blended on the conveyor 2112. The conveyor 2112 supplies the blended raw material of the secondary sintering raw material group 21 to a granulator. The blended raw material of the secondary sintering raw material 11 is then mixed and granulated in the granulator to produce a granulated product 24 of pseudo-particles. The granulator is preferably, for example, a combination of a high-speed stirring mixer 22 and a dish-type pelletizer 23 in this order. The granulator is not limited to the above example, as long as the former has a high mixing and stirring function and the latter has a high granulation function.

表2に副焼結原料群21の構成例を示す。副焼結原料群21の混合率は配合原料全体(主焼結原料11及び副焼結原料21の配合原料)の総質量に対して、15質量%~30質量%の範囲が良い。15質量%未満では生産性向上への効果が低く、30質量%を超えると設備能力不足で処理できない可能性がある。 Table 2 shows an example of the composition of the auxiliary sintering raw material group 21. The mixing ratio of the auxiliary sintering raw material group 21 is preferably in the range of 15% by mass to 30% by mass with respect to the total mass of the entire blended raw materials (the blended raw materials of the main sintering raw material 11 and the auxiliary sintering raw material 21). If it is less than 15% by mass, the effect of improving productivity is low, and if it exceeds 30% by mass, there is a possibility that processing will not be possible due to insufficient equipment capacity.

Figure 0007587142000002
Figure 0007587142000002

副焼結原料群21は、造粒を強化する対象である微粉原料211を主に含む。副造粒工程2において微粉原料211を選択的に造粒強化する。また、それは、主造粒工程1で造粒機として用いられるドラムミキサー12が、微粉原料211の造粒に不向きなためである。 The secondary sintered raw material group 21 mainly contains fine powder raw material 211, which is the target for strengthening granulation. In the secondary granulation process 2, the fine powder raw material 211 is selectively strengthened in granulation. This is because the drum mixer 12 used as a granulator in the main granulation process 1 is not suitable for granulating the fine powder raw material 211.

本願発明の特徴は、この微粉原料211が、ヘマタイト系微粉鉱石211aとマグネタイト系微粉鉱石211bとの混合物である点である。さらに、マグネタイト系微粉鉱石211bの混合率は、それとヘマタイト系微粉鉱石211aとの総質量に対して50質量%以上100質量%未満とされている。図2で説明したように、マグネタイト系微粉鉱石211bの混合率を50質量%以上とすることでマグネタイト系微粉鉱石を単独で使用した場合と同等の焼成後強度が得られる。 The feature of the present invention is that the fine powder raw material 211 is a mixture of hematite-based fine ore 211a and magnetite-based fine ore 211b. Furthermore, the mixing ratio of magnetite-based fine ore 211b is 50 mass% or more and less than 100 mass% with respect to the total mass of magnetite-based fine ore 211b and hematite-based fine ore 211a. As explained in FIG. 2, by making the mixing ratio of magnetite-based fine ore 211b 50 mass% or more, the same post-sintering strength as when magnetite-based fine ore is used alone can be obtained.

表2の実施態様1は、マグネタイト系微粉鉱石とヘマタイト系微粉鉱石の混合率をそれぞれ50質量%とした例である。ヘマタイト系微粉鉱石としては、例えば、ブラジル産やカナダ産の精鉱などが挙げられる。マグネタイト系微粉鉱石としては、北米産や南米産やヨーロッパ産やオーストラリア産やアフリカ産の精鉱などが挙げられる。 In embodiment 1 of Table 2, the mixing ratio of magnetite-based fine ore and hematite-based fine ore is 50 mass % each. Examples of hematite-based fine ore include concentrates from Brazil and Canada. Examples of magnetite-based fine ore include concentrates from North America, South America, Europe, Australia, and Africa.

微粉原料はそれぞれの鉄鉱山にて選鉱処理を経て出荷されることから、鉱物学的特性や処理プロセスに応じた所定の粒度分布を有する。粒度分布の測定手段としては篩通過重量率やレーザー回折・散乱法が挙げられ、評価指標としてはメディアン径(累積50質量%径)、平均粒度などが挙げられる。 Because the fine raw materials are shipped after being dressed at each iron mine, they have a certain particle size distribution according to their mineralogical characteristics and processing process. Methods for measuring particle size distribution include sieve passing weight rate and laser diffraction/scattering method, and evaluation indices include median diameter (cumulative 50% mass diameter) and average particle size.

上述の基礎的検討結果において、ヘマタイト系微粉鉱石とマグネタイト系微粉鉱石が共に63~125μmのH粗+M粗の組合せの場合は焼成後強度が低かったが、その他の組合せでは十分な強度が得られた。また、H細、M細の組み合わせ、及びH細、M粗の組み合わせでは特に焼成後強度が高くなった。従って本発明に記載の方法では、マグネタイト系微粉鉱石の粒度は、ヘマタイト系微粉鉱石の粒度以下であることが好ましい。また、ヘマタイト系微粉鉱石の好ましい粒度は125μm未満、マグネタイト系微粉鉱石の好ましい粒度は45μm未満である。より好ましくはヘマタイト系微粉鉱石とマグネタイト系微粉鉱石の両方の粒度が45μm未満の場合である。マグネタイト系微粉鉱石の粒度は小さければ小さいほど生産率等が向上する傾向がある。マグネタイト系微粉鉱石のさらに好ましい粒度は15μm以下である。また、いずれの微粉鉱石においても、粒度の下限値に特に制限はない。 In the above-mentioned basic study results, the post-sintering strength was low in the case of the combination of H-coarse + M-coarse, in which both the hematite-based fine ore and the magnetite-based fine ore were 63 to 125 μm, but sufficient strength was obtained in other combinations. In addition, the post-sintering strength was particularly high in the combination of H-fine and M-fine, and in the combination of H-fine and M-coarse. Therefore, in the method described in the present invention, it is preferable that the particle size of the magnetite-based fine ore is equal to or smaller than the particle size of the hematite-based fine ore. In addition, the preferred particle size of the hematite-based fine ore is less than 125 μm, and the preferred particle size of the magnetite-based fine ore is less than 45 μm. More preferably, the particle sizes of both the hematite-based fine ore and the magnetite-based fine ore are less than 45 μm. The smaller the particle size of the magnetite-based fine ore, the more the productivity and the like tend to improve. The more preferred particle size of the magnetite-based fine ore is 15 μm or less. Additionally, there is no particular lower limit on the particle size for any of the fine ores.

副造粒工程2において微粉原料の造粒を促進するために、造粒の核となる粉鉱石(核用鉱石)212を合わせて用いてもよい。微粉鉱石と粉鉱石(核用鉱石)の質量比を1.5/1以上3/1未満(微粉鉱石/粉鉱石)とすると最も造粒後の造粒物の強度が高くなる。核用鉱石としては、通常焼結鉱の製造で使用されるシンターフィード(以下、SFと記す。)であればよい。具体的には、褐鉄鉱系の鉱石が、当該鉱石を造粒核としたときの微粉原料の付着性が強い点で、好ましい。表2に示す実施態様2は、豪州産の褐鉄鉱を核用鉱石として1/3質量%(微粉鉱石及び粉鉱石の総質量に対する質量%)使用した例である。 In order to promote the granulation of the fine raw material in the secondary granulation process 2, fine ore (core ore) 212, which serves as the nucleus of granulation, may be used in addition. The strength of the granulated product after granulation is highest when the mass ratio of the fine ore to the fine ore (core ore) is 1.5/1 or more and less than 3/1 (fine ore/fine ore). The core ore may be sinter feed (hereinafter referred to as SF), which is usually used in the production of sintered ore. Specifically, limonite-based ores are preferred because the fine raw material has strong adhesion when the ore is used as a granulation nucleus. The embodiment 2 shown in Table 2 is an example in which 1/3 mass% (mass% of the total mass of the fine ore and the fine ore) of Australian limonite is used as the core ore.

微粉原料の造粒を促進するために、生石灰などのバインダーを適宜用いることができる。生石灰の場合は副焼結原料の総質量に対して5質量%以下で用いることが好ましい。実施態様3は、実施態様2に加えて生石灰を配合原料全体の総質量に対して0.5質量%(副焼結原料の総質量に対して2.2質量%)使用した例である。 To promote granulation of the fine powder raw materials, a binder such as quicklime can be used as appropriate. In the case of quicklime, it is preferable to use 5 mass% or less of the total mass of the auxiliary sintering raw materials. In embodiment 3, in addition to embodiment 2, quicklime is used in an amount of 0.5 mass% of the total mass of the entire blended raw materials (2.2 mass% of the total mass of the auxiliary sintering raw materials).

その他、副造粒工程2の配合原料には、微粉原料の造粒を阻害しない範囲で任意の焼結原料を含めることができる。 In addition, the raw materials mixed in the secondary granulation process 2 can contain any sintered raw materials as long as they do not inhibit the granulation of the fine powder raw materials.

本発明の実施可能性及び効果を確認するために、図3の造粒処理において、副造粒工程の微粉鉱石の使用割合が、焼結鉱生産性と焼結鉱強度に及ぼす影響を焼結鍋試験で調査した。その結果を実施例として、次に説明する。本発明は、この一実施例に限定されるものではない。本発明は、本発明の要旨を逸脱せず、本発明の目的を達成する限りにおいて、種々の条件を採用し得るものである。 In order to confirm the feasibility and effectiveness of the present invention, a sinter pot test was conducted to investigate the effect of the ratio of fine ore used in the secondary granulation process on sinter productivity and sinter strength in the granulation process shown in Figure 3. The results are described below as an example. The present invention is not limited to this example. Various conditions can be adopted in the present invention as long as they do not deviate from the gist of the present invention and the object of the present invention is achieved.

(実験装置)
焼結実験に用いた実験装置の主仕様を表3に、実験装置の構成を図4に示す。焼結鍋は、鍋本体とその下部に有する風箱から成る。風箱には熱電対が挿入されており、その温度が最高値を示す時点に基づいて焼結完了点を判定する。風箱には圧力計が挿入されており、鍋下での負圧を計測している。風箱と吸引ブロワとが配管で接続される。その配管には、ガス成分分析計(成分分析装置)につながるガス採取プローブ(成分分析用ポンプ)、および、流速計測用のオリフィス流量計が設けられている。点火炉は点火時には焼結鍋の上部に、焼結時には退避位置に移動可能なように設けられている。原料の造粒に用いる造粒機(図不示)は、主ライン用にドラム型、副ライン用にアイリッヒ型とパン型のバッチ式のものをそれぞれ用意した。
(Experimental Equipment)
The main specifications of the experimental equipment used in the sintering experiment are shown in Table 3, and the configuration of the experimental equipment is shown in Figure 4. The sintering pot consists of the pot body and a wind box located below it. A thermocouple is inserted in the wind box, and the sintering completion point is determined based on the point at which the temperature reaches its maximum. A pressure gauge is inserted in the wind box to measure the negative pressure under the pot. The wind box is connected to the suction blower by piping. The piping is equipped with a gas sampling probe (pump for component analysis) connected to a gas component analyzer (component analysis device), and an orifice flow meter for measuring the flow rate. The ignition furnace is installed above the sintering pot during ignition and can be moved to a retreat position during sintering. The granulators (not shown) used to granulate the raw materials were drum-type for the main line and Eirich-type and pan-type batch-type for the side line.

Figure 0007587142000003
Figure 0007587142000003

(実験方法および条件)
(原料配合)
本実施例においては、ヘマタイト系微粉鉱石211aとしてブラジル産の鉱石H1、マグネタイト系微粉鉱石211bとしてスウェーデン産の鉱石M1をそれぞれ用いた。粒度はレーザー回折・散乱法により測定して平均粒度を算出したところ、それぞれ26μmと19μmだった。
(Experimental Method and Conditions)
(Raw material blend)
In this embodiment, the hematite-based fine ore 211a was made of ore H1 produced in Brazil, and the magnetite-based fine ore 211b was made of ore M1 produced in Sweden. The particle sizes were measured by a laser diffraction/scattering method, and the average particle sizes were calculated to be 26 μm and 19 μm, respectively.

さらに、より細粒のマグネタイト系微粉鉱石を使用した場合の検証例として、オーストラリア産マグネタイト系微粉鉱石M2を用いた。平均粒度は14μmだった。 Furthermore, as a verification example of the use of finer magnetite-based fine ore, Australian magnetite-based fine ore M2 was used. The average particle size was 14 μm.

表4及び表5に、主造粒工程と副造粒工程の原料配合を示す。主造粒工程の原料配合は全て一定とした。副造粒工程におけるマグネタイト系微粉鉱石とヘマタイト系微粉鉱石の混合率を(主焼結原料及び副焼結原料の配合原料の総質量に対して)合計で15.0質量%とし、そのうちのマグネタイト系微粉鉱石の混合率(ヘマタイト系微粉鉱石及びマグネタイト系微粉鉱石の総質量に対する質量%)を、0質量%、25質量%、50質量%、75質量%、100質量%に変更する試験を行った。また、造粒の核となる粉鉱石(核用鉱石)を合わせて用いた。核用鉱石は豪州産の褐鉄鉱(粉鉱石)とした。核用鉱石の混合率は(主焼結原料及び副焼結原料の配合原料の総質量に対して)7.5質量%で一定とした。 Tables 4 and 5 show the raw material blends for the main granulation process and the secondary granulation process. The raw material blends for the main granulation process were all constant. The mixing ratio of magnetite-based fine ore and hematite-based fine ore in the secondary granulation process was set to a total of 15.0 mass% (relative to the total mass of the blended raw materials of the main sintering raw materials and the secondary sintering raw materials), and tests were conducted in which the mixing ratio of magnetite-based fine ore (mass% relative to the total mass of the hematite-based fine ore and the magnetite-based fine ore) was changed to 0 mass%, 25 mass%, 50 mass%, 75 mass%, and 100 mass%. In addition, fine ore (core ore) that serves as the nucleus of granulation was also used. The core ore was limonite (fine ore) from Australia. The mixing ratio of the core ore was set to a constant 7.5 mass% (relative to the total mass of the blended raw materials of the main sintering raw materials and the secondary sintering raw materials).

Figure 0007587142000004
Figure 0007587142000004

Figure 0007587142000005
Figure 0007587142000005

ここで、焼結プロセスにおいては慣例的に、焼成時の副成品として発生し原料として循環再利用される返鉱と、焼成時に燃焼し消失する粉コークス等の炭材は外数で表す。これらを除く、いわゆる新原料の合計が100質量%となり、返鉱、炭材を加えた全原料は119.7質量%となる。 In the sintering process, it is customary to include return ore, which is generated as a by-product during firing and recycled as a raw material, and carbonaceous materials such as coke powder that are burned and lost during firing. The total of so-called new raw materials excluding these is 100% by mass, and the total raw materials including return ore and carbonaceous materials is 119.7% by mass.

(造粒)
主造粒工程では、主焼結原料、返鉱および粉コークスを、ドラムミキサーに投入し、2分間転動して各原料を混合した。その後、水分量が7.0%になるように、ミキサー内に所定量の水を注水しながら各原料をさらに3分45秒間転動し、造粒を行った。
(Granulation)
In the main granulation process, the main sinter raw material, return ore and fine coke were charged into a drum mixer and mixed for 2 minutes. After that, the raw materials were further granulated by rolling for 3 minutes and 45 seconds while pouring a predetermined amount of water into the mixer so that the moisture content was 7.0%.

副造粒工程では、副焼結原料を高速攪拌ミキサーに投入し、水を添加して1分間混合攪拌した。ついで、混合物をパンペレタイザーに1wet-kgで投入していき、排出された造粒物を順次回収した。 In the secondary granulation process, the secondary sintering raw materials were fed into a high-speed agitating mixer, water was added, and the mixture was mixed and stirred for 1 minute. Next, the mixture was fed into a pan pelletizer at 1 wet-kg, and the discharged granules were collected one by one.

ついで、主造粒工程と副造粒工程のそれぞれで製造した造粒物を、前記ドラムミキサーで15秒間軽混合することで、これらの造粒物を合わせた。 Next, the granules produced in the main granulation process and the secondary granulation process were lightly mixed in the drum mixer for 15 seconds to combine these granules.

(鍋焼成)
前記造粒工程で製造した造粒物(合わせた造粒物)を焼結鍋に装入することで、原料充填層を形成した。ついで、原料充填層の表面を点火し時間計測を開始した。ここに、点火は、風量一定(1.5Nm/min)での下方吸引を継続しながら点火炉で原料充填層の表面を1300℃で1分間加熱することにより行った。点火後、9.8kPaの一定の鍋下負圧で原料充填層を焼成した。焼成終了時点は、排ガス温度(風箱に設置した熱電対で計測)が最大値を示した時間とし、点火開始から焼成終了時点までを焼成時間とした。焼成終了時点から3分後、ブロワを停止し、鍋から焼結ケーキを回収した。なお、熱電対は焼結鍋の中層、下層、鍋下にも配置し、それぞれの温度変化を測定した。
(Pot roasting)
The granulated material (combined granulated material) produced in the granulation process was charged into a sintering pot to form a raw material packed bed. Next, the surface of the raw material packed bed was ignited and time measurement was started. Here, ignition was performed by heating the surface of the raw material packed bed at 1300°C for 1 minute in an ignition furnace while continuing downward suction at a constant air volume (1.5 Nm 3 /min). After ignition, the raw material packed bed was fired at a constant negative pressure below the pot of 9.8 kPa. The firing end time was the time when the exhaust gas temperature (measured by a thermocouple installed in the wind box) showed a maximum value, and the firing time was the time from the start of ignition to the end of firing. Three minutes after the end of firing, the blower was stopped and the sintered cake was collected from the pot. Thermocouples were also placed in the middle layer, lower layer, and under the pot of the sintering pot to measure the temperature changes in each layer.

焼成終了後に得られた焼結ケーキは、高さ2mから4回落下させた後、直径5mmの角型の篩で分級し、その篩上を成品焼結鉱として、+5mmの成品歩留を評価した。また、焼成時間と成品歩留から、生産率を算出した。 The sintered cake obtained after the firing was dropped four times from a height of 2 m, then classified using a square sieve with a diameter of 5 mm. The sieve-surface was regarded as the product sintered ore, and the product yield of +5 mm was evaluated. In addition, the productivity was calculated from the firing time and the product yield.

(実験結果)
試験結果を表6に示す。
生産率は、副造粒工程における微粉原料がヘマタイト微粉のみの比較例1に対して、マグネタイト系微粉鉱石の混合率25質量%の比較例2では変化がなかったが、混合率50質量%の実施例1から向上が認められ、混合率75質量%の実施例2では、概ねマグネタイト微粉のみの参考例に近い値が得られた。
(Experimental Results)
The test results are shown in Table 6.
The productivity did not change between Comparative Example 1, in which the fine powder raw material in the secondary granulation process was only hematite fine powder, and Comparative Example 2, in which the mixing ratio of magnetite-based fine ore was 25% by mass. However, an improvement was observed from Example 1, in which the mixing ratio was 50% by mass, and Example 2, in which the mixing ratio was 75% by mass, obtained a value roughly close to that of the reference example, in which only magnetite fine powder was used.

粒度に関しては、マグネタイト系微粉鉱石の混合率50質量%で、より細粒のマグネタイト系微粉鉱石M2を用いた実施例3において、実施例1よりも高い生産率が得られた。 Regarding particle size, a higher production rate was obtained in Example 3, which used finer magnetite-based fine ore M2 at a mixing ratio of 50 mass% magnetite-based fine ore, than in Example 1.

Figure 0007587142000006
Figure 0007587142000006

(結論)
焼結実験においても、前述の基礎試験の結果が確認された。すなわち、マグネタイト系微粉鉱石の混合率を50質量%以上とすること、さらに粒度に関してはヘマタイト系微粉鉱石と比較してより細粒のマグネタイト系微粉鉱石を配合することで、ヘマタイト系微粉鉱石単独よりも高い生産性が得られることを確認した。
(Conclusion)
The results of the basic test described above were also confirmed in the sintering experiment. That is, it was confirmed that by setting the mixing ratio of magnetite-based fine ore to 50 mass% or more and further blending magnetite-based fine ore having a finer particle size than hematite-based fine ore, higher productivity can be obtained than by blending hematite-based fine ore alone.

以上、本発明の好適な実施形態について詳細に説明したが、本発明はかかる例に限定されない。本発明の属する技術の分野における通常の知識を有する者であれば、特許請求の範囲に記載された技術的思想の範疇内において、各種の変更例または修正例に想到し得ることは明らかであり、これらについても、当然に本発明の技術的範囲に属するものと了解される。 Although the preferred embodiment of the present invention has been described in detail above, the present invention is not limited to such examples. It is clear that a person with ordinary knowledge in the technical field to which the present invention pertains can conceive of various modified or revised examples within the scope of the technical ideas described in the claims, and it is understood that these also naturally fall within the technical scope of the present invention.

焼成後の焼結鉱の強度の低下を抑制しつつ、マグネタイト系微粉鉱石を購入容易なヘマタイト系微粉鉱石に置換することが可能な焼結鉱の製造方法に利用することができる。 It can be used in a sintered ore manufacturing method that can replace magnetite-based fine ore with easily purchased hematite-based fine ore while suppressing the decrease in strength of the sintered ore after firing.

1:主造粒工程
11:主焼結原料
12:ドラムミキサー
13:12にて製造した造粒物
2:副造粒工程
21:副焼結原料群
211:造粒を強化する対象の微粉原料
211a:ヘマタイト系微粉鉱石
211b:マグネタイト系微粉鉱石
212:核用鉱石
22:高速撹拌ミキサー
23:皿型ペレタイザー
24:22、23にて製造した造粒物
3:主造粒工程と副造粒工程で製造したそれぞれの造粒物
4:焼結機
1: Main granulation process 11: Main sintering raw material 12: Drum mixer 13: Granules produced in 12 2: Secondary granulation process 21: Secondary sintering raw material group 211: Fine raw material to be granulated intensively 211a: Hematite-based fine ore 211b: Magnetite-based fine ore 212: Core ore 22: High-speed stirring mixer 23: Plate-type pelletizer 24: Granules produced in 22 and 23 3: Granules produced in the main granulation process and the secondary granulation process 4: Sintering machine

Claims (5)

焼結原料を、主焼結原料と微粉鉱石を含む副焼結原料とに分け、前記主焼結原料を混合及び造粒する主造粒工程と、前記副焼結原料として微粉鉄鉱石と粉鉱石とバインダーを混合及び造粒する副造粒工程とを並列で行い、前記主造粒工程と前記副造粒工程で製造したそれぞれの造粒物を合わせ、前記合わせた造粒物を焼成する焼結鉱の製造方法であって、
前記副造粒工程に用いられる前記微粉鉱石がマグネタイト系微粉鉱石とヘマタイト系微粉鉱石の混合物であって、前記マグネタイト系微粉鉱石の、前記マグネタイト系微粉鉱石と前記ヘマタイト系微粉鉱石との総質量に対する混合率が50質量%以上100質量%未満であることを特徴とする焼結鉱の製造方法。
A method for producing sintered ore, comprising the steps of: dividing a sintering raw material into a main sintering raw material and a secondary sintering raw material containing fine iron ore; carrying out a main granulation process in which the main sintering raw material is mixed and granulated; and a secondary granulation process in which fine iron ore, fine iron ore, and a binder are mixed and granulated as the secondary sintering raw material in parallel; combining the granules produced in the main granulation process and the secondary granulation process; and firing the combined granules,
The fine ore used in the secondary granulation step is a mixture of magnetite-based fine ore and hematite-based fine ore, and a mixing ratio of the magnetite-based fine ore to the total mass of the magnetite-based fine ore and the hematite-based fine ore is 50 mass% or more and less than 100 mass%.
前記粉鉱石は、褐鉄鉱であることを特徴とする、請求項1に記載の焼結鉱の製造方法。The method for producing sintered ore according to claim 1, wherein the fine ore is limonite. 前記マグネタイト系微粉鉱石の粒度は、前記ヘマタイト系微粉鉱石の粒度以下であることを特徴とする、請求項1または2記載の焼結鉱の製造方法。 3. The method for producing sintered ore according to claim 1 , wherein the particle size of the magnetite-based fine ore is equal to or smaller than that of the hematite-based fine ore. 前記マグネタイト系微粉鉱石の粒度が19μm以下であることを特徴とする、請求項3に記載の焼結鉱の製造方法。The method for producing sintered ore according to claim 3, characterized in that the magnetite-based fine ore has a particle size of 19 μm or less. 前記副焼結原料がさらに粉鉱石を含み、前記微粉鉱石と前記粉鉱石の質量比が1.5/1以上3/1未満であることを特徴とする請求項1から4のいずれか1項に記載の焼結鉱の製造方法。 5. The method for producing sintered ore according to claim 1, wherein the auxiliary sintering raw material further contains fine ore, and a mass ratio of the fine ore to the fine ore is 1.5/1 or more and less than 3/1.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004018716A1 (en) 2002-08-21 2004-03-04 Nippon Steel Corporation Method of granulating sintering material for iron manufacturing
JP2013253281A (en) 2012-06-06 2013-12-19 Nippon Steel & Sumitomo Metal Corp Method for producing sintered ore
JP2016176122A (en) 2015-03-20 2016-10-06 株式会社神戸製鋼所 Pseudo particles for sintered ore production
JP2016191122A (en) 2015-03-31 2016-11-10 新日鐵住金株式会社 Method for producing sintered ore

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004018716A1 (en) 2002-08-21 2004-03-04 Nippon Steel Corporation Method of granulating sintering material for iron manufacturing
JP2013253281A (en) 2012-06-06 2013-12-19 Nippon Steel & Sumitomo Metal Corp Method for producing sintered ore
JP2016176122A (en) 2015-03-20 2016-10-06 株式会社神戸製鋼所 Pseudo particles for sintered ore production
JP2016191122A (en) 2015-03-31 2016-11-10 新日鐵住金株式会社 Method for producing sintered ore

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