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JPS6223094B2 - - Google Patents
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JPS6223094B2 - - Google Patents

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Publication number
JPS6223094B2
JPS6223094B2 JP55151408A JP15140880A JPS6223094B2 JP S6223094 B2 JPS6223094 B2 JP S6223094B2 JP 55151408 A JP55151408 A JP 55151408A JP 15140880 A JP15140880 A JP 15140880A JP S6223094 B2 JPS6223094 B2 JP S6223094B2
Authority
JP
Japan
Prior art keywords
yarn
warp
irritation
transmission
unevenness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP55151408A
Other languages
Japanese (ja)
Other versions
JPS5696937A (en
Inventor
Toshio Yamaoku
Kenichi Nakaishi
Masamichi Ueki
Haruhiko Kusakabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP15140880A priority Critical patent/JPS5696937A/en
Publication of JPS5696937A publication Critical patent/JPS5696937A/en
Publication of JPS6223094B2 publication Critical patent/JPS6223094B2/ja
Granted legal-status Critical Current

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Description

【発明の詳細な説明】[Detailed description of the invention]

本発明はインターレース処理された熱可塑性合
成繊維マルチフイラメントからなるタテ糸を実質
的に無ヨリ無ノリで製織する方法に関し、従来の
無ヨリ無ノリ織物で問題となる透過光により見え
る“透過ムラ”欠点および反射光により見える
“光沢ムラ”欠点のない高品位の織物を得る製織
方法に関するものである。 従来衣料用の合成繊維マルチフイラメントを用
いて織物を製造する際、タテ糸には製織時の毛羽
発生防止のためヨリを与えかつノリを付与する方
法がとられてきた。これら加ネンおよびノリ付の
各工程は製織作業能率上やむを得ず経る工程であ
つて所要コスト低減の観点から省略したいという
のが業界の願望であつた。ヨリ、ノリの効果に替
るべき有効な手段として特公昭37−1175などのご
とき、空気処理により糸条の単糸間に絡みあいを
付与したいわゆるインターレース糸をタテ糸に用
い、無ヨリ無ノリで製織することが一部こころみ
られている。このようなインターレース処理を行
なうことにより適用単糸繊度、織物密度などの面
で無ヨリ無ノリで製織可能な範囲が拡大されより
多くの織物品種にわたり、製織準備工程の合理化
が行なわれ、さらにはノリ抜き工程の省略による
精練染色工程の簡略化が実現可能となり、その効
果は大きい。しかしながら、非嵩高性の合成繊維
のインターレース糸をタテ糸として無ヨリ無ノリ
で製織した織物には、タテ方向に透過光により見
える微少単位の“透過ムラ”欠点および反射光に
より見える微少単位の“光沢ムラ”欠点が発生し
織物品位を著しく低下させる欠点を有している。
本発明者らはこの“透過ムラ”および“光沢ム
ラ”欠点の解消をはかるためまず発生原因につい
て鋭意研究した結果次のような事実が判明した。
すなわち“透過ムラ”欠点は、インターレースの
有無に関係なく無ヨリ無ノリ織物にのみ発生する
特有の欠点で織物を形成するタテ糸のマルチフイ
ラメント構成単糸の配列状態が糸の長さ方向およ
びタテ糸間において変化するために、各単糸の重
なり方に差が生じその結果この織物に入つた光が
透過するとき透過方向に片よりが生じ、これが
“透過ムラ”となるいわゆる“透過イラツキ”欠
点である。 また、同一要因によるものと思われていた“光
沢ムラ”には2種類の異なる原因によるものが存
在することが判明した。すなわちその1つはイン
ターレース糸の構造的特徴に起因するものであつ
て、いわゆる“単糸交絡ムラ”と称される欠点で
ある。インターレース糸には、単糸が交絡された
集束部と交絡のない非集束部が交互に存在してい
るので、この糸形態のちがいが織物を構成した後
も残存し光沢ムラとなるものである。もう1つは
インターレースの有無に関係なく、無ヨリ無ノリ
織物を形成するタテ糸のマルチフイラメント構成
単糸の配列状態が変化するために、タテ糸の偏平
度に差のあるものが混在し、それぞれのタテ糸に
交錯するヨコ糸に屈曲の差を与える結果、ヨコ糸
の屈曲差が織物の光沢ムラとなるいわゆる“反射
イラツキ”欠点である。これらの欠点は一般に強
度、伸度ともに高くタフで無ヨリ無ノリ化に耐え
うる潜在的性能をもつており、かつ通常断面が円
形でつやがあり、糸の幾何学的構造が光の通過特
性および光沢特性に敏感に現れ易い性質の有る合
成繊維が出現してきた結果、無ヨリ無ノリで製織
することが望みうる状態になつて初めて表面化す
るものであるが、現在までの段階でその内容と対
策について具体的な提案が公表されていない。 本発明者らは、インターレース糸を無ヨリで使
うことにより発生するところの“単糸交絡ムラ”
欠点およびインターレースの有無に無関係に無ヨ
リ無ノリで製織することにより発生する“透過イ
ラツキ”および“反射イラツキ”欠点の物理的発
生機構を明らかにし、“単糸交絡ムラ”欠点およ
び“透過イラツキ”欠点のない無ヨリ無ノリ織物
の製造方法を提案するとともに、さらに“反射イ
ラツキ”欠点をも同時に解決する無ヨリ無ノリ織
物の製造方法を提案する。本発明は高品位の無ヨ
リ無ノリ織物の製造方法に関し、次の如き構成を
有することを特徴とする。 すなわち、本発明は、インターレース処理され
た熱可塑性合成繊維マルチフイラメントからなる
糸条のCF値が10〜100である糸をタテ糸として使
用し、かつ当該タテ糸を構成する単糸の直径をd
(mm)、モノフイラメントと仮定したときの総直径
をD(mm)、タテ糸間隔をx(mm)、およびヨコ糸
間隔をz(mm)として数式 0.250≧d/x+0.472D/z を満足し、かつテ糸を構成する単糸の直径d
(mm)とタテ糸単糸数fとの積yとタテ糸間隔x
(mm)の間に定義した一次式 0.46x+0.283≦y≦0.20x+0.404 を満足するように実質的に無ヨリ無ノリで製織す
る方法である。ここで実質的に無ヨリ無ノリとは
50T/m程度以下の原糸元ヨリは有してもよく、
要は製織前に特にネン糸をしないことを意味す
る。 以下本発明を詳細に説明する。 前述の如く、無ヨリ無ノリ織物に発生する欠点
は、その発生原因の異なる3種の欠点、すなわち
“単糸交絡ムラ”、“透過イラツキ”および“反射
イラツキ”に大別される。以下それぞれの欠点の
解決法について詳述する。 まず反射光によつて見える2つの“光沢ムラ”
のうち集束部と非集束部の糸形態差からなる“単
糸交絡ムラ”欠点の解消方法について述べる。こ
の“単糸交絡ムラ”はインターレース処理された
タテ糸を用いて無ヨリまたは無ヨリ無ノリで製織
した時に生じる欠点であり、インターレース処理
された糸の原糸CF値、無ヨリ無ノリで製織した
織物の生機分解タテ糸のCF値および織物の“単
糸交絡ムラ”欠点との関係を調査した結果、表1
の結果を得た。すなわち“単糸交絡ムラ”欠点と
原糸CF値の間には密接な関係があり、インター
レース処理後の原糸CF値が80を越えると特に100
以上になると“単糸交絡ムラ”欠点が目立ち問題
となり、原糸のCF値が100以下、望ましくは80以
下であれば“単糸交絡ムラ”は解消する。生機タ
テ糸のCF値は、原糸CF値、および油剤の種類と
は無関係に製織準備、製織の工程を経ると減少
し、特にウオータージエツトルームで無ヨリかつ
無ノリで製織した場合、水の影響を受けて大幅に
減少する結果10以下になり、ほとんど同一レベル
にそろつてしまうことを把握した。この結果から
生機において認められる、“単糸交絡ムラ”欠点
は原糸の交絡度に応じて残留する交絡の幾何学的
なごりであり、CF値に現われるような実質的な
カラマリは数が少なくかつその差もごく少ないこ
とから“単糸交絡ムラ”との関係はうすいことが
わかる。すなわち単糸のからまりのほとんどが単
なる重なり合いに近い程度まで弱められている
が、この重なり合いの形と頻度により“単糸交絡
ムラ”欠点が発生すると考えられる。この交絡の
幾何学的なごりが光学的欠点となる境界域が原糸
のCF値80〜100近辺のものと対応するものであ
る。一方、製織性の面から考えた原糸のCF値の
適正値については、原糸CF値と製織性の間には
密接な関係があり、CF値が少なすぎる場合、た
とえばCF値10以下の場合には単糸分離がおこり
易く単糸切れが増加し製織性が低下するため原糸
のCF値は10以上、望ましくは20以上が好まし
い。 上述の如く、“単糸交絡ムラ”を解消するため
には、原糸のCF値が100以下、好ましくは80以下
であることを要し、製織性の面からは最低10以上
必要である。 なお本特許に述べるCF値はU.S.P2985995に準
ずる測定法によるものであり、試長約1mの試料
下端にトータルデニールx0.2gの荷重をつるし、
試料上端の糸束中央部に直径0.7mmのクロムメツ
キをほどこしたフツクを挿入し虫ピンでささえな
がら約1cm/secの速度で静かにフツクを落下さ
せ交絡部で停止するまでの距離E(cm)を求め
る。フツクの総重量は単糸デニール相当のグラム
数とする。50回の測定を行ない、その平均値から
CF値=100/Eを求めるものとする。 上述のCF値条件をみたして作られた無ヨリ無
ノリ織物には、“単糸交絡ムラ”による光沢ムラ
は発生しないが、別の欠点として透過光によつて
のみ見えるいわゆる“透過イラツキ”が普通条件
下で製織した時しばしば織物全面に発生し、衣料
用として商品価値を著しく低下させている。従つ
てこの“透過イラツキ”欠点をも解消しなけれ
ば、実用性のある無ヨリ無ノリ織物を完成させた
ことにはならないのである。 以下、“透過イラツキ”欠点の発生原因および
その解決法について述べる。“透過イラツキ”欠
点は第1図に示すごとく、タテ糸のみに輝きの差
が認められ、かつ光の入射方向は入射面とヨコ糸
が平行な状態で強くまた入射角度が変わると“透
過イラツキ”欠点の発生個所が変化して見え、反
対に光の入射方向がタテ糸と平行な状態では“透
過イラツキ”欠点は認められない。この欠点を解
消するために、発生原因を解析した結果、次のよ
うな事実が判明した。すなわち無ヨリ無ノリで製
織された生機を構成するタテ糸は、無ヨリ無ノリ
で織られたため、このタテ糸を構成する各単糸が
平行にきちんと整列されて並べられた形態とな
り、糸としての断面形状を加ネン糸にくらべて見
ると偏平な状態になる。さらにタテ糸単糸の配列
状態が図2に示すごとく例えば2段配列をとる糸
の場合2段目に配列しているフイラメントの重な
り方に差が認められ、2段目配列フイラメントが
1段目配列フイラメントに対して安定状態よりわ
ずか左寄りに重なつたもの(第2図−A)とわず
か右寄りに重なつたもの(第2図−B)があり、
この両者の発生比率は約50%づつである。かかる
状態の部分へ入射面とヨコ糸が平行な状態で光が
照射されると2段目配列フイラメントが1段目配
列フイラメントに対して安定状態よりわずかに左
よりに重なつたところでは透過した光の大部分が
左の方向へ、右よりに重なつたところでは透過し
た光の大部分が右の方向へ進む、つまり透過した
光の大部分が目に入つたところでは輝いて見え、
透過した光の大部分が目に入らないところでは黒
く見える。この輝く部分と黒く見える部分の差が
透過ムラとなり、いわゆる“透過イラツキ”が発
生する。また“透過イラツキ”の強さは2段目配
列フイラメントが1段目配列フイラメントに対し
て安定状態よりわずかに片よつたところの面積と
ここを通過した光の透過光量により決定される。
なおタテ糸のフイラメントの配列状態が3段およ
び4段に配列されている部分では、3段および4
段目に配列されているフイラメントのすぐ下に配
列されているフイラメントに対して安定状態より
わずかにずれても、透過光の方向のかたよりが少
ないため“イラツキ”は発生しないが、タテ糸の
各フイラメントの配列がすべて3段および4段配
列をしていても、3段目および4段目に配列され
たフイラメントは本数が少ないため、1本のタテ
糸のすべての部分で3段および4段に配列してい
るのではなく必ず2段配列されている部分があ
り、この部分で2段目配列フイラメントが1段目
配列フイラメントに対して安定状態よりわずかに
片よつた場合には“透過イラツキ”が発生する。
このフイラメントの配列状態に影響をおよぼす要
素は種々の実験の結果、タテ糸を構成している単
糸の直径d(mm)、タテ糸の総繊度T(デニー
ル)、タテ密度K(本/2.54cm)、ヨコ密度L
(本/2.54cm)であり、これら4要素のある組合
せにおいてのみこの“透過イラツキ”が解消し得
ることを明らかにした。すなわちタテ糸繊度T
(デニール)をこれがモノフイラメントと仮定し
た場合の直径D(mm)に、タテ糸密度K(本/
2.54cm)をタテ糸間隔x(2.54/Kmm)に、およ
びヨコ糸密度L(本/2.54cm)をヨコ糸間隔z
(2.54/Kmm)に置換えると、“透過イラツキ”欠
点を解消しうる組合せは 0.250≧d/x+0.472D/z このましくは0.217≧d/x+0.472D/z の条件を満足する時のみである。したがつて、
“透過イラツキ”の問題とならない無ヨリ無ノリ
織物を得るためには、上記数式の領域に入るよ
う、タテ糸の総繊度と単糸直径およびタテ、ヨコ
密度の組合せを選択すればよい。具体的にはタテ
糸の総繊度および単糸直径の選択にあたつては、
それぞれの総繊度に応じて計画される織物密度の
全領域にて“透過イラツキ”欠点が発生しない単
糸直径を選択するのが望ましい。 たとえば、ナイロンの70デニール使い平織物
で、比較的よく用いられるタテ密度100〜115本/
in、ヨコ密度75〜90の範囲で“透過イラツキ”欠
点の少ない無ヨリ無ノリ織物を得ようとするなら
ば、単糸直径は0.0208mm以下すなわち単糸数とし
て20以上を選択すれば全領域にわたつて“透過イ
ラツキ”欠点の少ない無ヨリ無ノリ織物を得るこ
とが出来る。 以上のように“透過イラツキ”欠点を防止する
前記領域内にある如く、総繊度、単糸直径、タ
テ、ヨコ密度を選択し、かつ前述の“単糸交絡ム
ラ”欠点を防止するために導き出した「原糸CF
値が100以下、望ましくは80以下」また製織性を
満足するための「原糸CF値10以上」という条件
を満足する如く設定して、無ヨリ無ノリ製織を行
なうことにより始めて、“透過イラツキ”および
“単糸交絡ムラ”欠点のない高品位の無ヨリ無ノ
リ平織物が得られる。 次に別の要因によるもう1つの反射光により見
える“光沢ムラ”いわゆる“反射イラツキ”があ
り、この“反射イラツキ”欠点をも解消すれば、
さらに望ましい最高品位の無ヨリ無ノリ織物が完
成するわけである。以下、“反射イラツキ”の発
生原因、およびその解決法について詳述する。
“反射イラツキ”は第3図Aに示すごとく、タテ
方向に全面に強く光る輝線部が雨降り状に認めら
れたり、又は第3図Bに示すごとく明暗部が斑点
状に認められたりするものである。なお強く光る
輝線部は一見タテ方向の連続線に見えるが、第3
図Cのごとくヨコ糸の強く光る部分が、タテ方向
に点線状につらなるものである。欠点を解消する
ため、種々の実験を行なつた結果、次のような事
実が判明した。 すなわち原糸のCF値が80以下の場合、生機に
なつたタテ糸の単糸交絡はほとんど消滅した形と
なり、その結果、各単糸が平行にきちんと整列さ
れて並べられた形態となり、糸としての断面形状
を加ネン糸に比べてみると偏平な状態になる。ま
た単糸のつみ重ね状態も糸に集束力がないため、
織込み時の周辺条件の影響を受けて変化しやす
く、偏平度の異なるものが混在しやすい。タテ糸
断面の偏平度の異なるものが混在すると、それぞ
れのタテ糸に交錯するヨコ糸の屈曲度に差が生じ
る。かかる状態の部分へ光が照射されると第4図
Aに示すごとくヨコ糸の屈曲率が大きい部分では
弱い反射光となり、第4図Bに示す如くヨコ糸の
屈曲率が小さい部分では強い反射光となる。つま
り弱い反射光と強い反射光のものが混在すること
になり、強い反射光の占める割合が弱い反射光の
占める割合より少ない場合に雨降り状の“輝線状
イラツキ”となり、逆に多い場合には、“斑点状
イラツキ”となる。このタテ糸断面形状の偏平度
の異なるものの混在状態を次式のように“偏平部
含有率”0〜5%および80〜100%の範囲であれ
ば“反射イラツキ”品位は合格するということを
見い出した。 偏平部含有率(%)=A/A+B×100 ここでA、Bは織物断面の顕微鏡観察によつて
求める。すなわちタテ糸内の各単糸の配列状態が
2段配列をとるものと、3段配列をとるものが混
在している場合には、2段配列をとる(例えば第
4図Bのような状態)経糸本数をA、3段配列を
とる(例えば第4図Aのような状態)タテ糸本数
をBとする。また3段配列と4段配列が混在する
場合においても低段配列側のタテ糸本数をA、高
段配列側のタテ糸本数をBとする。なお単糸の配
列状態を配列段数の種類のみでみた場合は、2種
類の混在が大部分で3種以上の混在はほとんどな
い。従つて偏平部含有率を0〜5%および80〜
100%にするような対策をとれば“反射イラツ
キ”品位は合格することになる。そこで種々の対
策を研究し実験の結果、偏平部含有率に影響をお
よぼす要素は、タテ密度K(本/2.54cm)、タテ
糸単糸直径d(mm)およびタテ糸単糸数f(本)
であり、それら3要素のある組合せにおいてのみ
偏平部含有率を0〜5%および80〜100%にする
ことが可能であることを明らかにした。すなわち
タテ糸密度K(本/2.54cm)をタテ糸間隔x
(2.54/Kmm)に置換え、かつタテ糸単糸直径d
(mm)とタテ糸単糸数fの積d×f(mm)をyと
すると偏平部含有率を0〜5%および80〜100%
にすることが可能な組合せは第6図の領域であ
る。なおy=d×f(mm)の意味は1本の糸を構
成する各単糸がすべて1段配列をとつて並んだ場
合の糸幅を表わしている。第6図の意味は、yが
xより大きくなつていくにしたがい、単糸の配列
状態が2段、かつ3段、4段配列へと進行してい
くことを示しており、2〜3段、3段、3〜4段
配列の各々の進行過程で配列段数の異なるものが
混在することを示している。第6図の偏平部含有
率が0〜5%および80〜100%の領域すなわち
“反射イラツキ”欠点が合格する領域を数式で表
わすと次のようになる。すなわち、 0.46x+0.283≦y≦0.20x+0.404 の領域となる。 したがつて無ヨリ無ノリ織物で発生する“透過
イラツキ”と“単糸交絡ムラ”および“反射イラ
ツキ”の3大欠点をすべて防止するためには、前
述の“透過イラツキ”と“単糸交絡ムラ”を防止
するための条件を満足させ、かつ上記“反射イラ
ツキ”欠点を防止する。前記領域内に入るよう、
タテ密度と総繊度および単糸数の組合せを選択
し、すべての条件を満足するごとく設定して、無
ヨリ無ノリで製織することにより始めて可能とな
る。 具体的に前述のナイロン70デニール使い平織物
を例にとつて説明するならば、計画されるタテ、
ヨコ密度を前述の範囲と同じとした場合、“透過
イラツキ”および“単糸交絡ムラ”の合格する単
糸数は20フイラメント以上であつて、さらに“反
射イラツキ”をも合格する単糸数は20〜24さらに
望ましくは20〜22の間から選択すればよい。 以上のように“単糸交絡ムラ”欠点を防止する
ために導き出した「原糸CF値が100以下、望まし
くは80以下」また製織性を満足するための「原糸
CF値10以上」という条件を満足し、かつ“透過
イラツキ”欠点を防止する前記領域内にある如
く、総繊度、単糸直径、タテ、ヨコ織密度を選択
することにより、“透過イラツキ”欠点のない無
ヨリ無ノリ織物が得られ、さらに“反射イラツ
キ”欠点を防止する前記領域内にある如く、総繊
度、単糸直径、タテ織密度を選択すれば、“透過
イラツキ”と“反射イラツキ”欠点のない高品位
の無ヨリ無ノリ平織物が得られるのである。 本発明により加ネン工程およびノリ付工程が省
略されるため製造コストが切り下げられることは
勿論のことであるが、ウオータジエツトルームに
て製織する場合、通常のノリ付与にみられる綜
絖、筬などへのノリ脱落がなく、したがつて、カ
ビの発生や、綜絖相互のクツツキにより発生する
織物のタテシマ欠点が少なくなる特長があり、さ
らに製織工程においても生機乾燥ノリ抜き精練、
生機セツトなどの工程のいくつか、または全部を
省略することも可能性があり、合理化に寄与する
程度は大きい。 次に実施例にしたがつて説明する。 実施例 表2に示すようなポリアミド系およびポリエス
テル系マルチフイラメント糸条を製造し、表3の
種々の製品規格で加ネンおよびノリ付を行なわず
に製織した結果を表4に示した。 なお織機条件は、いずれも機種はウオータ・ジ
エツト・ルームで織機回転数360r.p.mとし、織
機張力は、ポリアミド系フイラメント糸の場合
0.25〜0.30g/d、ポリエステル系フイラメント
糸の場合0.30〜0.35g/dに設定して製織した。 表4に示す如く、本発明の範囲内に入るように
製織した水準1〜2および9〜10は、インターレ
ース処理され、加ネンノリ付工程を省略したにも
かかわらず“単糸交絡ムラ”が全くなく、かつ
“透過イラツキ”および“反射イラツキ”が3級
以上の合格水準の高品位の織物が得られた。 しかし水準3、4、11、12の如く、原糸のCF
値が100以下で かつ、d/x+0.472×D/z≦0.250の領域内にある
場合 でも、なお0.46x+0.283≦y≦0.20x+0.404の領
域外にある場合には、“単糸交絡ムラ”および
“透過イラツキ”は満足しても“反射イラツキ”
品位は2級以下の不合格品であつた。 逆に水準、8の如く、本発明の d/x+0.472×D/z≦0.250 および0.46x+0.283≦y≦0.20x+0.404 の関係を満足しても、原糸CF値が100以上のも
の、すなわち本発明の領域外にある場合には、
“透過イラツキ”および“反射イラツキ”は合格
したが、“単糸交絡ムラ”品位が悪く、不合格品
であつた。もちろん水準6、13の如く、原糸CF
値を満足しても d/x+0.472×D/z および0.46x+0.283≦y≦0.20x+0.404 が本発明外のものは、“透過イラツキ”および
“反射イラツキ”品位ともに不合格となつた。 なお、製織性に関してはCF値30以上を採用し
ているため、製織効率90%以上であり良好であつ
た。
The present invention relates to a method for weaving warp yarns made of interlaced thermoplastic synthetic fiber multifilament with virtually no twist or glue, and to solve the problem of "transmission unevenness" that is visible due to transmitted light, which is a problem with conventional kink-free and glue-free fabrics. The present invention relates to a weaving method for obtaining high-quality fabrics that are free from defects and "uneven gloss" defects visible by reflected light. Conventionally, when producing textiles using synthetic multifilament fibers for clothing, a method has been used in which the warp yarns are given twist and texture to prevent the generation of fuzz during weaving. These welding and gluing steps are unavoidable steps in terms of weaving efficiency, and it has been the desire of the industry to omit them from the perspective of reducing required costs. As an effective means to replace the effects of twist and glue, a so-called interlaced yarn, which is created by air treatment to create intertwining between the single yarns of the yarn, is used as the warp yarn, such as in Japanese Patent Publication No. 37-1175. There is some interest in weaving. By performing such interlacing processing, the range in which it is possible to weave without twisting or sagging in terms of applicable single yarn fineness, fabric density, etc. is expanded, more fabric types are covered, the weaving preparation process is streamlined, and the weaving preparation process is streamlined. By omitting the glue removal process, the scouring and dyeing process can be simplified, and the effect is significant. However, woven fabrics woven with non-bulky synthetic fiber interlaced yarns as warp yarns without any twists or glues have defects such as minute "transmission unevenness" visible in the vertical direction when transmitted light and minute "transmission unevenness" visible when reflected light. It has the disadvantage of causing "unevenness in gloss" and significantly lowering the quality of the fabric.
In order to eliminate the defects of "uneven transmission" and "uneven gloss", the inventors of the present invention first conducted extensive research into the causes of their occurrence, and as a result, the following facts were discovered.
In other words, the "uneven transmission" defect is a unique defect that occurs only in non-twisted and non-swept fabrics, regardless of the presence or absence of interlacing. Due to the change between the yarns, there is a difference in the way each single yarn overlaps, and as a result, when the light that enters the fabric is transmitted, there is unevenness in the transmission direction, which is called "transmission unevenness". This is a drawback. Furthermore, it has been discovered that the "unevenness in gloss", which was thought to be caused by the same factor, is caused by two different causes. That is, one of them is caused by the structural characteristics of interlace yarns, and is a defect called "unevenness in single yarn entanglement." Interlaced yarns alternately have convergent areas where the single yarns are intertwined and non-aggregated areas where the single yarns are not intertwined, so this difference in yarn form remains even after the fabric is constructed, causing uneven gloss. . The other problem is that regardless of the presence or absence of interlacing, the arrangement of the multifilament single yarns in the warp yarns that form the warp-free fabric changes, so warp yarns with different degrees of flatness coexist. As a result of giving different bends to the weft yarns that intersect with each warp yarn, the difference in bending of the weft yarns causes uneven gloss of the fabric, which is a so-called "reflection irritation" defect. These drawbacks are that the yarn is generally tough and has high strength and elongation, and has the potential to withstand twist-free and no-knead treatment, and the cross section is usually circular and glossy, and the geometric structure of the yarn has good light transmission characteristics. As a result of the emergence of synthetic fibers with properties that are sensitive to gloss and luster properties, this will only come to the fore when it becomes possible to weave it without any twist or glue. No specific proposals for countermeasures have been made public. The present inventors have discovered that "single yarn intertwining unevenness" occurs when interlaced yarn is used without twisting.
We clarified the physical generation mechanism of "transmission irregularity" and "reflection irregularity" defects that occur due to weaving without any twist or glue, regardless of the presence or absence of defects and interlacing, and investigated the "single yarn entanglement unevenness" defect and "transmission irregularity." We propose a method for producing a kink-free, non-glue-free fabric that has no defects, and also a method for producing a kink-free, non-glue fabric that solves the defect of "reflection irritation" at the same time. The present invention relates to a method for manufacturing a high-quality kink-free fabric, and is characterized by having the following configuration. That is, in the present invention, a yarn made of interlaced thermoplastic synthetic fiber multifilament having a CF value of 10 to 100 is used as a warp yarn, and the diameter of the single yarn constituting the warp yarn is d.
(mm), assuming that it is a monofilament, the total diameter is D (mm), the warp thread spacing is x (mm), and the weft thread spacing is z (mm), satisfying the formula 0.250≧d/x+0.472D/z and the diameter d of the single yarn constituting the thread
(mm), product y of warp thread single thread number f, and warp thread spacing x
This is a method of weaving with substantially no twist or glue so as to satisfy the linear equation 0.46x+0.283≦y≦0.20x+0.404 defined between (mm). Here, what is essentially no twist and no nori?
The yarn may have a twist of around 50T/m or less,
In short, this means that you don't particularly use flax yarn before weaving. The present invention will be explained in detail below. As mentioned above, the defects that occur in kink-free and non-glue fabrics can be broadly classified into three types with different causes: "unevenness in single yarn entanglement,""transmissionirregularity," and "reflection irregularity." Solutions to each of these drawbacks will be explained in detail below. First, there are two “uneven gloss” visible due to reflected light.
Among these, we will discuss how to solve the problem of "single yarn entanglement unevenness" caused by the difference in yarn form between the bundled part and the non- bundled part. This "single yarn intertwining unevenness" is a defect that occurs when interlaced warp yarns are woven with no twist or no twist and no weave. As a result of investigating the relationship between the CF value of the biodegradable warp yarn of the woven fabric and the defect of "single yarn entanglement unevenness" of the woven fabric, Table 1
The results were obtained. In other words, there is a close relationship between the defect of "single yarn entanglement unevenness" and the yarn CF value, and especially when the yarn CF value after interlace processing exceeds 80,
If this is the case, the defect of "single yarn entanglement unevenness" becomes noticeable and becomes a problem, and if the CF value of the raw yarn is 100 or less, preferably 80 or less, "single yarn entanglement unevenness" will be eliminated. The CF value of gray warp yarn decreases through the weaving preparation and weaving processes, regardless of the raw yarn CF value and the type of oil agent. As a result, it was found that the number decreased significantly due to the influence of From this result, the "unevenness in single yarn entanglement" observed in gray fabrics is due to the geometric imperfections of entanglement that remain depending on the degree of entanglement of the raw yarns, and the substantial calamari that appears in the CF value is small in number and Since the difference is very small, it can be seen that there is only a weak relationship with "unevenness in single fiber entanglement." In other words, most of the entanglements of single yarns are weakened to the extent that they are almost like simple overlaps, but it is thought that the form and frequency of this overlap causes the defect of "uneven entanglement of single yarns." The boundary region where this geometrical entanglement causes an optical defect corresponds to the CF value of the raw yarn, which is around 80 to 100. On the other hand, regarding the appropriate value of the CF value of yarn from the viewpoint of weavability, there is a close relationship between yarn CF value and weavability. In such cases, the CF value of the raw yarn is preferably 10 or more, preferably 20 or more, since single yarn separation is likely to occur, resulting in increased single yarn breakage and reduced weavability. As mentioned above, in order to eliminate "single yarn entanglement unevenness", it is necessary that the CF value of the raw yarn is 100 or less, preferably 80 or less, and from the viewpoint of weavability, it is necessary to have a CF value of at least 10 or more. The CF value described in this patent is based on a measurement method based on USP2985995, in which a load of total denier x 0.2g is suspended at the bottom end of a sample with a sample length of approximately 1m.
Insert a chrome-plated hook with a diameter of 0.7 mm into the center of the yarn bundle at the top of the sample, and while supporting it with an insect pin, gently drop the hook at a speed of approximately 1 cm/sec until it stops at the intertwined part, distance E (cm). seek. The total weight of the hook shall be the number of grams equivalent to the single yarn denier. Perform 50 measurements and calculate from the average value
Assume that CF value = 100/E is to be determined. Non-kink and non-glue fabrics made under the above CF value conditions do not have uneven luster due to single yarn entanglement unevenness, but another drawback is so-called "transmission irregularity" that is visible only through transmitted light. This often occurs on the entire surface of the fabric when weaving under normal conditions, significantly reducing its commercial value as a garment. Therefore, unless this "transmission irritation" defect is also resolved, a practical kink-free fabric will not be completed. Below, we will discuss the cause of the "transmission irritation" defect and how to solve it. As shown in Figure 1, the defect of "transmission irritation" is that the difference in brightness is observed only in the warp threads, and the incident direction of the light is strong when the incident plane and the weft thread are parallel, and when the angle of incidence changes, "transmission irritation" occurs. ``The location of the defect appears to change, and conversely, when the incident direction of light is parallel to the warp threads, the ``transmission irritation'' defect is not observed. In order to eliminate this drawback, we analyzed the cause and found the following facts. In other words, the warp threads that make up the gray fabric are woven without any twists or glues, so the individual single threads that make up the warp threads are neatly aligned in parallel, forming a shape that can be used as a thread. When you compare the cross-sectional shape of the thread to the thread, it becomes flat. Furthermore, as shown in Figure 2, when the warp yarn is arranged in two tiers, for example, there is a difference in the way the filaments arranged in the second tier overlap, and the filaments in the second tier are arranged in the first tier. There are two types of filaments that overlap slightly to the left of the stable state (Figure 2-A) and those that overlap slightly to the right (Figure 2-B).
The incidence rate of both cases is approximately 50% each. When light is irradiated to a part in such a state with the plane of incidence and the weft parallel to each other, the light is transmitted when the second-stage filament overlaps the first-stage filament slightly to the left compared to the stable state. Most of the light goes to the left, and where it overlaps to the right, most of the transmitted light goes to the right.In other words, where most of the transmitted light hits the eye, it appears to shine,
Where most of the transmitted light does not reach the eye, it appears black. The difference between the bright parts and the black parts causes uneven transmission, which is what is called "transmission irritating." The strength of "transmission irritation" is determined by the area where the second-stage filament is slightly deviated from the stable state with respect to the first-stage filament and the amount of light transmitted therethrough.
In addition, in the parts where the filaments of the warp thread are arranged in 3 and 4 stages,
Even if there is a slight deviation from the stable state with respect to the filaments arranged directly below the filaments arranged in the row, "irritation" does not occur because the direction of the transmitted light is small, but each of the warp threads Even if all the filaments are arranged in 3 and 4 rows, the number of filaments arranged in the 3rd and 4th rows is small, so all parts of one warp yarn have 3 and 4 rows. There is always a part where the filaments are arranged in two tiers rather than in a straight line, and if the second tier filament deviates slightly from the stable state with respect to the first tier filament in this area, "transmission irritation" occurs. ” occurs.
As a result of various experiments, the factors that influence the filament arrangement state are the diameter d (mm) of the single yarns constituting the warp yarns, the total fineness T (denier) of the warp yarns, and the warp density K (strands/2.54 cm), horizontal density L
(book/2.54cm), and it was revealed that this "transmission irritation" could be resolved only by a certain combination of these four elements. In other words, warp yarn fineness T
(denier) is the diameter D (mm) assuming that it is a monofilament, and the warp thread density K (strands/
2.54cm) to warp thread spacing x (2.54/Kmm), and weft thread density L (pieces/2.54cm) to weft thread spacing z
(2.54/Kmm), the combination that can eliminate the "transmission irritation" defect is only when the condition of 0.250≧d/x+0.472D/z, preferably 0.217≧d/x+0.472D/z, is satisfied. It is. Therefore,
In order to obtain a kink-free fabric that does not cause the problem of "transmission irritation," the combination of the total fineness of the warp yarns, the single yarn diameter, and the warp and weft densities may be selected so as to fall within the range of the above formula. Specifically, when selecting the total fineness and single yarn diameter of warp yarns,
It is desirable to select a single yarn diameter that does not cause the "transmission irritation" defect over the entire range of fabric densities planned for each total fineness. For example, a relatively common 70-denier nylon plain weave with a vertical density of 100 to 115 fibers/
In, if you want to obtain a kink-free fabric with less "transmission irritation" defects in the weft density range of 75 to 90, select a single yarn diameter of 0.0208 mm or less, or a single yarn count of 20 or more, to cover the entire area. It is possible to obtain a kink-free fabric with less "transmission irritation" defects during wadding. As mentioned above, the total fineness, single yarn diameter, warp, and weft density are selected so as to be within the above-mentioned range to prevent the defect of "transmission irregularity", and the values are determined in order to prevent the defect of "uneven entangling of single yarn" mentioned above. "Original Yarn CF
By setting the conditions such that the fiber CF value is 100 or less, preferably 80 or less, and the yarn CF value is 10 or more to satisfy weavability, and weaving without any twist or glue, we can eliminate ``transmission irritation''. A high-quality, twist-free, non-swept plain woven fabric free from the defects of ``unevenness'' and ``single yarn entanglement unevenness'' can be obtained. Next, there is "unevenness in gloss" that is visible due to another reflected light due to another factor, so-called "reflection irritation", and if this "reflection irritation" drawback is also eliminated,
Furthermore, the desired highest quality kink-free fabric is completed. Hereinafter, the cause of "reflection irritation" and its solution will be explained in detail.
"Reflection irritation" is a phenomenon in which bright lines that shine strongly in the vertical direction are observed over the entire surface in a raindrop pattern, as shown in Figure 3A, or bright and dark areas are observed in spots as shown in Figure 3B. be. At first glance, the bright line that shines brightly appears to be a continuous line in the vertical direction, but it is actually a third line.
As shown in Figure C, the strongly glowing parts of the weft thread are connected in a dotted line in the vertical direction. In order to eliminate the drawbacks, various experiments were conducted and the following facts were found. In other words, when the CF value of the raw yarn is 80 or less, the interlacing of the single yarns in the warp yarn that becomes the gray fabric almost disappears, and as a result, each single yarn is neatly arranged in parallel, and the yarn becomes If you compare the cross-sectional shape of the yarn to that of the Kanen yarn, it will be in a flat state. In addition, since the threads do not have a converging force in the stacked state of single threads,
It tends to change due to the influence of surrounding conditions during weaving, and items with different flatness tend to coexist. When warp yarns with different degrees of flatness in cross section coexist, there will be differences in the degree of curvature of the weft yarns that intersect with each warp yarn. When light is irradiated to a part in such a state, as shown in Fig. 4A, the reflected light is weak in the part where the curvature of the weft thread is large, and as shown in Fig. 4B, it is strongly reflected in the part where the curvature of the weft thread is small. Becomes light. In other words, weak reflected light and strong reflected light will coexist, and if the proportion of strong reflected light is smaller than the proportion of weak reflected light, it will result in rain-like "bright line irritation," and conversely, if there is a large amount of reflected light, , resulting in “spotted irritation”. The mixed state of warp yarn cross-sectional shapes with different degrees of flatness can be expressed as follows: If the "flattening content" ranges from 0 to 5% and from 80 to 100%, the quality of "reflection irritation" passes. I found it. Flat part content (%)=A/A+B×100 Here, A and B are determined by microscopic observation of the cross section of the fabric. In other words, if the arrangement state of each single yarn in a warp thread is a two-tier arrangement and a three-tier arrangement, the two-tier arrangement is used (for example, the state shown in Figure 4 B). ) The number of warp threads is A, and the number of warp threads is B in a three-tier arrangement (for example, the state shown in FIG. 4A). Further, even in the case where a three-tier arrangement and a four-tier arrangement coexist, the number of warp threads on the lower arrangement side is A, and the number of warp threads on the higher arrangement side is B. Note that when looking at the arrangement state of single yarns only in terms of the number of rows, two types are mixed in most cases, and three or more types are rarely mixed. Therefore, the flat part content is 0~5% and 80~
If you take measures to make it 100%, you will pass the "reflection irritation" quality test. Therefore, we researched various countermeasures, and as a result of experiments, we found that the factors that affect the flat part content are warp density K (strands/2.54 cm), warp yarn single yarn diameter d (mm), and warp yarn single yarn number f (pieces).
It was clarified that it is possible to make the flat part content from 0 to 5% and from 80 to 100% only with certain combinations of these three elements. In other words, warp thread density K (pieces/2.54cm) is warp thread spacing x
(2.54/Kmm) and warp yarn single yarn diameter d
(mm) and the product d x f (mm) of warp yarn single yarn number f is y, then the flat part content is 0 to 5% and 80 to 100%.
Possible combinations are in the area shown in FIG. The meaning of y=d×f (mm) represents the yarn width when all the single yarns constituting one yarn are arranged in one row. The meaning of Figure 6 is that as y becomes larger than x, the arrangement of single yarns progresses to 2, 3, and 4 stages. , 3-stage array, and 3-4 stage arrays, in which different numbers of array stages coexist. The areas in which the content of the flat portions in FIG. 6 is 0 to 5% and 80 to 100%, that is, the areas where the "reflection irritating" defect passes, can be expressed using the following formula. That is, the area is 0.46x+0.283≦y≦0.20x+0.404. Therefore, in order to prevent all three major drawbacks of "transmission irregularity", "single yarn entanglement unevenness", and "reflection irregularity" that occur in non-twist and no-glue fabrics, it is necessary to It satisfies the conditions for preventing "unevenness" and prevents the above-mentioned "reflection irritation" drawback. To enter the area,
This is only possible by selecting a combination of warp density, total fineness, and number of single yarns, setting them so that all conditions are satisfied, and weaving without twisting or gluing. To explain specifically using the above-mentioned nylon 70 denier plain weave as an example, the planned vertical,
If the weft density is the same as the above range, the number of filaments that passes "transmission irritation" and "single yarn entanglement unevenness" is 20 filaments or more, and the number of filaments that also passes "reflection irritation" is 20 or more. 24, more preferably from 20 to 22. As mentioned above, in order to prevent the defect of "single yarn entanglement unevenness", "raw yarn CF value is 100 or less, preferably 80 or less" and to satisfy weavability, "raw yarn CF value is 100 or less, preferably 80 or less"
By selecting the total fineness, single yarn diameter, warp, and weft density within the above range that satisfies the condition of "CF value of 10 or more" and prevents the "transmission irritation" defect, the "transmission irritation" defect can be avoided. If the total fineness, single yarn diameter, and warp weave density are selected to be within the above-mentioned range that prevents the defect of "transmission irritation" and "reflection irritation" ``You can obtain a high-quality plain woven fabric without any defects. It goes without saying that the manufacturing cost is reduced because the weaving process and the gluing process are omitted by the present invention, but when weaving in a water jet loom, the heddles, reeds, etc. that are seen in normal gluing processes are reduced. There is no slipping off of the glue, which reduces the occurrence of mold and warp defects in the fabric that occur due to mutual stickiness of the healds.Furthermore, in the weaving process, it is possible to dry the gray fabric, remove the glue, and scouring it.
It is also possible to omit some or all of the steps such as setting the gray fabric, which greatly contributes to rationalization. Next, an explanation will be given according to an example. Examples Polyamide-based and polyester-based multifilament yarns as shown in Table 2 were produced and woven according to the various product specifications shown in Table 3 without being coated or glued, and the results are shown in Table 4. The loom conditions are as follows: All models have a water jet room, the loom rotation speed is 360 rpm, and the loom tension is for polyamide filament yarn.
Weaving was carried out at a setting of 0.25 to 0.30 g/d, and in the case of polyester filament yarn, 0.30 to 0.35 g/d. As shown in Table 4, Levels 1 to 2 and 9 to 10, which were woven within the scope of the present invention, were interlaced and had no "unevenness in single yarn entanglement" even though the addition process was omitted. A high-quality woven fabric was obtained, which was free from irradiation and had a passing level of grade 3 or higher in terms of "transmission irradiation" and "reflection irritation." However, as in levels 3, 4, 11, and 12, the CF of the yarn
Even if the value is 100 or less and is within the area of d/x+0.472×D/z≦0.250, if it is still outside the area of 0.46x+0.283≦y≦0.20x+0.404, Even if "uneven confounding" and "transmission irregularities" are satisfied, "reflection irregularities"
The quality of the product was 2nd grade or lower, and it was a rejected product. On the other hand, as in Level 8, even if the relationships of d/x+0.472×D/z≦0.250 and 0.46x+0.283≦y≦0.20x+0.404 of the present invention are satisfied, the yarn CF value is 100 or more. i.e. outside the scope of the present invention,
Although it passed the test for "transmission irritation" and "reflection irritation," the quality of "single yarn entanglement unevenness" was poor and the product was rejected. Of course, like levels 6 and 13, yarn CF
Even if the values are satisfied, if d/x+0.472×D/z and 0.46x+0.283≦y≦0.20x+0.404 are outside the scope of the present invention, the quality will be rejected for both “transmission irritation” and “reflection irritation”. Ta. Regarding weavability, since a CF value of 30 or more was adopted, the weaving efficiency was 90% or more, which was good.

【表】【table】

【表】【table】

【表】【table】

【表】【table】

【表】【table】 【図面の簡単な説明】[Brief explanation of the drawing]

第1図は透過光による“イラツキ”欠点の略図
である。第2図はタテ糸断面と光の透過状態の略
図でAは1段配列単糸に対して2段配列単糸がわ
ずかに左へ片よつた場合、Bは右へ片よつた場合
を示す図である。第3図は反射光による“イラツ
キ”欠点の略図でAは“輝線状イラツキ”、Bは
“斑点状イラツキ”、Cは“輝線状イラツキ”の輝
線部の拡大図である。第4図は織物断面と光の反
射状態の略図でAはタテ糸を構成する単糸が3段
目配列をとつた場合、Bは2段配列をとつた場合
を示す図である。第5図は透過光による“イラツ
キ”欠点、第6図は反射光による“イラツキ”欠
点が発生しない領域の図示である。
FIG. 1 is a schematic representation of the "irritating" defect due to transmitted light. Figure 2 is a schematic diagram of the warp yarn cross section and the state of light transmission. A shows the case where the two-tiered single yarn is slightly shifted to the left compared to the single-tiered single yarn, and B shows the case where it is shifted to the right. It is a diagram. FIG. 3 is a schematic diagram of "irritation" defects caused by reflected light, where A is a "bright line irritating", B is a "spotted irritating", and C is an enlarged view of a bright line part of a "bright line irritating". FIG. 4 is a schematic diagram of the cross section of the fabric and the state of light reflection, where A shows the case where the single yarns constituting the warp threads are arranged in the third row, and B shows the case where they are arranged in the second row. FIG. 5 is an illustration of an area where the "irritation" defect due to transmitted light does not occur, and FIG. 6 is an illustration of an area where the "irritation" defect due to reflected light does not occur.

Claims (1)

【特許請求の範囲】 1 インターレース処理された熱可塑性合成繊維
マルチフイラメントからなる糸条のCF値が10〜
100である糸をタテ糸として使用し、かつ当該タ
テ糸の単糸直径d(mm)、モノフイラメントと仮
定したときの総直径D(mm)、タテ糸間隔x
(mm)およびヨコ糸間隔z(mm)の間の関係が下
式 0.250≧d/x+0.472D/z を満足し、かつ、当該タテ糸の単糸直径d(mm)
とタテ糸単糸数f(本)との積yとタテ糸間隔x
(mm)との間に定義した一次式 0.46x+0.283≦y≦0.20x+0.404 を満足するように、実質的に無ヨリ、無ノリで製
織することを特徴とする無ヨリ、無ノリ織物の製
造法。
[Claims] 1. The CF value of the yarn made of interlaced thermoplastic synthetic fiber multifilament is 10-10.
100 is used as the warp yarn, and the single yarn diameter d (mm) of the warp yarn, the total diameter D (mm) assuming it is a monofilament, and the warp yarn spacing x
(mm) and the weft yarn spacing z (mm) satisfies the following formula: 0.250≧d/x+0.472D/z, and the single yarn diameter d (mm) of the warp yarn
The product of y and the number of single warp threads f (pieces) and the warp thread spacing x
(mm) A twist-free and glue-free fabric that is characterized by being woven with virtually no twist or glue so as to satisfy the linear equation 0.46x+0.283≦y≦0.20x+0.404 defined between manufacturing method.
JP15140880A 1980-10-30 1980-10-30 Production of nontwisted nonsized fabric Granted JPS5696937A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15140880A JPS5696937A (en) 1980-10-30 1980-10-30 Production of nontwisted nonsized fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15140880A JPS5696937A (en) 1980-10-30 1980-10-30 Production of nontwisted nonsized fabric

Publications (2)

Publication Number Publication Date
JPS5696937A JPS5696937A (en) 1981-08-05
JPS6223094B2 true JPS6223094B2 (en) 1987-05-21

Family

ID=15517937

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15140880A Granted JPS5696937A (en) 1980-10-30 1980-10-30 Production of nontwisted nonsized fabric

Country Status (1)

Country Link
JP (1) JPS5696937A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58129012A (en) * 1982-01-28 1983-08-01 Nitto Kasei Kk Preparation of antifouling emulsion of copolymer containing triorganotin salt

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5130621B2 (en) * 1971-09-06 1976-09-02
JPS49132370A (en) * 1973-04-05 1974-12-19
JPS49132371A (en) * 1973-04-19 1974-12-19
JPS5319067B2 (en) * 1973-07-17 1978-06-19
JPS50148667A (en) * 1974-05-20 1975-11-28

Also Published As

Publication number Publication date
JPS5696937A (en) 1981-08-05

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