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JPH0628240B2 - Metalorganic vapor phase growth equipment - Google Patents
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JPH0628240B2 - Metalorganic vapor phase growth equipment - Google Patents

Metalorganic vapor phase growth equipment

Info

Publication number
JPH0628240B2
JPH0628240B2 JP29397687A JP29397687A JPH0628240B2 JP H0628240 B2 JPH0628240 B2 JP H0628240B2 JP 29397687 A JP29397687 A JP 29397687A JP 29397687 A JP29397687 A JP 29397687A JP H0628240 B2 JPH0628240 B2 JP H0628240B2
Authority
JP
Japan
Prior art keywords
growth chamber
lid
wafer
growth
chamber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP29397687A
Other languages
Japanese (ja)
Other versions
JPH01136329A (en
Inventor
成典 高岸
英樹 森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissin Electric Co Ltd
Sumitomo Electric Industries Ltd
Original Assignee
Nissin Electric Co Ltd
Sumitomo Electric Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissin Electric Co Ltd, Sumitomo Electric Industries Ltd filed Critical Nissin Electric Co Ltd
Priority to JP29397687A priority Critical patent/JPH0628240B2/en
Publication of JPH01136329A publication Critical patent/JPH01136329A/en
Publication of JPH0628240B2 publication Critical patent/JPH0628240B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は有機金属気相成長法(Metal Organ
ic Vapor Phase Epitaxy,以
下、MOVPE法と略記する)を実施するための縦型気
相成長装置に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention is directed to metalorganic vapor phase epitaxy (Metal Organ).
ic Vapor Phase Epitaxy, hereinafter abbreviated as MOVPE method).

(従来の技術) 半導体装置の製造には、半導体基板上に半導体単結晶を
エピタキシャル成長させる方法が広く用いられている。
このエピタキシャル成長法のなかで、有機金属気相成長
法は、制御性がよく大量生産にも向いているところか
ら、半導体産業の中で重要な地位を占めつつある。この
方法はトリメチルガリウム(Ga(CH33)やトリメ
チルアルミニウム(Al(CH33)等の有機金属ガス
とアルシン(AsH3)やホスフイン(PH3)を原料と
して、それを熱分解させてエピタキシャル成長させる方
法である。この方法により製造されるエピタキシャル層
の特性は、成長装置内の雰囲気に強く依存する。即ち、
アルミニウムやアンチモン等の酸化し易い成分を含む半
導体の製造は、酸素や水分が僅か残留しても結晶の特性
を著しく劣化する。そこで、成長室内に酸素や水分の侵
入を防ぐために成長室を石英製からステンレス等の金属
製に変更し、配管継手部を溶接で接続するなど気密性を
高める方策がとられている。この金属製の成長室は強度
も大きく安全面からも好ましいものである。また、真空
準備室を設けて酸素、水分等の不純物を除いた後、ウエ
ハを成長室に移したりすることが行われてきた。
(Prior Art) A method of epitaxially growing a semiconductor single crystal on a semiconductor substrate is widely used for manufacturing a semiconductor device.
Among these epitaxial growth methods, the metal organic chemical vapor deposition method is occupying an important position in the semiconductor industry because it has good controllability and is suitable for mass production. This method uses organic metal gas such as trimethylgallium (Ga (CH 3 ) 3 ) or trimethylaluminum (Al (CH 3 ) 3 ) and arsine (AsH 3 ) or phosphine (PH 3 ) as a raw material and thermally decomposes them. Is a method of epitaxial growth. The characteristics of the epitaxial layer produced by this method strongly depend on the atmosphere in the growth apparatus. That is,
In the manufacture of a semiconductor containing a component such as aluminum or antimony that easily oxidizes, even if a small amount of oxygen or water remains, the crystal characteristics are significantly deteriorated. Therefore, in order to prevent oxygen and moisture from entering the growth chamber, measures such as changing the growth chamber from quartz to a metal such as stainless steel and connecting pipe joints by welding have been taken. This metal growth chamber has high strength and is preferable from the viewpoint of safety. In addition, a vacuum preparation chamber is provided to remove impurities such as oxygen and water, and then the wafer is transferred to a growth chamber.

(発明が解決しようとする問題点) しかし、この種の装置では、成長室に至る搬送管内がデ
ッドスペースとなり、成長室内の原料ガス流を乱す原因
となり、また、搬送管に設けたゲートバルブのシール部
に反応生成物が付着して、バルブの機密性を不完全なも
のとし、真空準備室の機能を低下させるなどの問題点が
あった。
(Problems to be solved by the invention) However, in this type of device, the inside of the transfer pipe leading to the growth chamber becomes a dead space, which causes disturbance of the raw material gas flow in the growth chamber, and also the gate valve provided in the transfer pipe. There is a problem that the reaction product adheres to the seal portion, the airtightness of the valve becomes incomplete, and the function of the vacuum preparation chamber is deteriorated.

本発明は、上記問題点を解消し、高純度の均一なエピタ
キシャル層の形成を可能とする有機金属気相成長装置を
提供しようとするものである。
The present invention is intended to solve the above-mentioned problems and to provide a metal-organic chemical vapor deposition apparatus capable of forming a highly pure uniform epitaxial layer.

(問題点を解決するための手段) 本発明は、縦型成長室の中央に半導体ウエハを装着する
回転式サセプタを配置し、該ウエハ上にエピタキシャル
成長を行う有機金属気相成長装置において、ウエハを予
め真空保持する真空準備室を設け、ゲートバルブを有す
る搬送管によって真空準備室と成長室を接続し、該搬送
管を介して成長室のサセプタにウエハを搬送する搬送機
構を設け、成長室の搬送用開口部に開閉可能な蓋を設
け、該蓋の内面は成長室内壁と同一材料で構成し、か
つ、蓋の装着時には成長室内壁と連続する滑らかな面を
有し、上記搬送管には蓋を移動して収納するための枝管
を付設し、枝管若しくは搬送管を真空排気系と接続する
ことを特徴とする有機金属気相成長装置である。
(Means for Solving the Problems) The present invention is a metal-organic chemical vapor deposition apparatus in which a rotary susceptor for mounting a semiconductor wafer is arranged in the center of a vertical growth chamber and epitaxial growth is performed on the wafer. A vacuum preparation chamber for holding a vacuum in advance is provided, the vacuum preparation chamber and the growth chamber are connected by a transfer pipe having a gate valve, and a transfer mechanism for transferring a wafer to the susceptor of the growth chamber via the transfer pipe is provided. The transfer opening is provided with a lid that can be opened and closed, and the inner surface of the lid is made of the same material as the growth chamber inner wall, and has a smooth surface that is continuous with the growth chamber inner wall when the cover is mounted. Is a metal-organic vapor phase epitaxy apparatus characterized in that a branch pipe for moving and accommodating a lid is attached, and the branch pipe or the transfer pipe is connected to a vacuum exhaust system.

(作用) 第一図は、本発明の1具体例である有機金属気相成長装
置の正面断面図である。エピタキシャル成長用半導体ウ
エハ17はホルダ7にセットされ、該ホルダ7はカセッ
ト8に納められ、扉5を開けて該カセット8はレール9
に沿って真空準備室2に挿入される。扉5を閉じた後、
上記準備室2は真空排気系3と接続して排気される。一
方、ステンレス製の成長室15は別の真空排気系20に
より真空に保持されている。上記準備室2及び成長室1
5を接続する搬送管13のゲートバルブ6を開け、ウエ
ハ17をホルダ7とともに搬送装置1によってカセット
8から取り出し、成長室15内のサセプタ16に装着す
る。第一図のサセプタ16はウエハホルダー7を4つ保
持して、回転機構21により回転する。成長室15の周
囲には冷却水流路22を設け、入口11から冷却水を導
入して出口10から排出する。ウエハ17の加熱用ヒー
タ18はサセプタ16の内側に設け、その端子19を成
長室15から引き出してある。そして、成長室15の頂
部は導管を介して原料ガス供給系4と接続している。一
方、成長室15の搬送用開口部には、蓋12が設けられ
ている。この蓋12は成長室15と同じ材料で作られて
おり、その内面は閉じた状態において成長室15の内壁
の一部として滑らかな面を形成する。そして、蓋12は
冷却水流路を有し、流路に接続する冷却水導管24によ
り背面より支持される。この冷却水導管24は、上記搬
送管13に付設する枝管23を通って外部に引き出され
ており、枝管23のベロー25の底部に固定されて駆動
装置26により前後に移動することができる。従って、
蓋12は搬送用開口部を閉じた状態から、図のように枝
管23内に収納することにより、搬送機構1の腕を真空
準備室2から成長室15のサセプタ16まで伸ばすこと
ができる。なお、枝管23は成長室15の真空排気系2
0と導管14で接続されており、成長室15と同様に真
空が保持される。それ故、蓋12は格別な気密性を要求
されない。
(Operation) FIG. 1 is a front sectional view of a metal-organic vapor phase epitaxy apparatus which is one specific example of the present invention. The semiconductor wafer 17 for epitaxial growth is set in a holder 7, the holder 7 is placed in a cassette 8, the door 5 is opened, and the cassette 8 is moved to a rail 9.
And is inserted into the vacuum preparation chamber 2. After closing the door 5,
The preparation chamber 2 is connected to the vacuum exhaust system 3 and is exhausted. On the other hand, the growth chamber 15 made of stainless steel is kept in vacuum by another vacuum exhaust system 20. Preparation room 2 and growth room 1
The gate valve 6 of the transfer pipe 13 for connecting 5 is opened, the wafer 17 together with the holder 7 is taken out of the cassette 8 by the transfer device 1, and mounted on the susceptor 16 in the growth chamber 15. The susceptor 16 of FIG. 1 holds four wafer holders 7 and is rotated by the rotating mechanism 21. A cooling water channel 22 is provided around the growth chamber 15, and cooling water is introduced from the inlet 11 and discharged from the outlet 10. The heater 18 for heating the wafer 17 is provided inside the susceptor 16, and its terminal 19 is drawn out from the growth chamber 15. The top of the growth chamber 15 is connected to the source gas supply system 4 via a conduit. On the other hand, the lid 12 is provided at the transfer opening of the growth chamber 15. The lid 12 is made of the same material as the growth chamber 15, and the inner surface thereof forms a smooth surface as a part of the inner wall of the growth chamber 15 in the closed state. The lid 12 has a cooling water channel and is supported from the back by a cooling water conduit 24 connected to the channel. The cooling water conduit 24 is drawn out through a branch pipe 23 attached to the carrier pipe 13, is fixed to the bottom of a bellows 25 of the branch pipe 23, and can be moved back and forth by a drive device 26. . Therefore,
The lid 12 can be extended from the vacuum preparatory chamber 2 to the susceptor 16 of the growth chamber 15 by accommodating the lid 12 in the branch pipe 23 as shown in the figure with the transport opening closed. The branch pipe 23 is the vacuum exhaust system 2 of the growth chamber 15.
0 and the conduit 14 are connected, and a vacuum is maintained like the growth chamber 15. Therefore, the lid 12 does not need to be particularly airtight.

このような蓋の採用により、ウエハの搬送時のみ該蓋を
開放するが、成長時には搬送管のデッドスペースを排除
し、滑らかな成長室内面を確保し、かつ、成長室を均一
に冷却することができるので、成長室の頂部から流下す
る原料ガス流を乱すこともなく、ウエハ上に均一なエピ
タキシャル成長を可能とする。また、この蓋によりゲー
トバルブが保護されるので、反応生成物がゲートバルブ
のシール部に付着することもなく気密が保持される。
By adopting such a lid, the lid is opened only when the wafer is transferred, but the dead space of the transfer tube is eliminated during growth, a smooth growth chamber inner surface is secured, and the growth chamber is cooled uniformly. Therefore, it is possible to perform uniform epitaxial growth on the wafer without disturbing the raw material gas flow flowing down from the top of the growth chamber. Further, since the gate valve is protected by this lid, the airtightness is maintained without the reaction product adhering to the seal portion of the gate valve.

所定の成長を終了した時に、成長室15の温度を下げ、
真空排気した後、ゲートバルブ6を開けて搬送装置1に
よりウエハ17をホルダ7とともにサセプタ16から取
り出して真空準備室2のカセット8に回収し、ゲートバ
ルブ6を閉じてから、大気圧にリークして扉5を開けて
ウエハ17を外部に取り出す。
When the predetermined growth is completed, the temperature of the growth chamber 15 is lowered,
After vacuum evacuation, the gate valve 6 is opened, the wafer 17 is taken out from the susceptor 16 together with the holder 7 by the transfer device 1 and collected in the cassette 8 in the vacuum preparation chamber 2, and after the gate valve 6 is closed, it leaks to the atmospheric pressure. Door 5 is opened to take out the wafer 17 to the outside.

(実施例) ステンレス製の成長室を採用した第一図の気相成長装置
を用いて、GaAsウエハにGaAs層及びAl0.3
0.4As層をエピタキシャル成長により形成してHE
MT構造を作成した。3インチのGaAsウエハをホル
ダにセットして真空準備室に移り、該室内を10-5〜1
-6Torrに真空排気した。一方、成長室は10-8
orr台まで真空排気されており、ゲートバルブを開け
て、ウエハをホルダとともに真空準備室から成長室に移
し、サセプタにセットした。その後、成長室の冷却水流
路に冷却水を流し、ヒータに通電してウエハを加熱し
て、ウエハの温度を成長温度である680℃とした。そ
れから、搬送管の蓋をして、サセプタを回転速度15r
pmで回転させながら原料ガスを成長室の頂部から流し
て気相成長を行った。原料ガス組成は、GaAs層の形
成時に、0℃に保持したトリメチルガリウムを水素でバ
ブリングしたガスを15.0cc/分、水素ベース10
%アルシンを1000cc/分を100分間流し、ま
た、Al0.3Ga0.7As層の形成時には、20℃に保持
したトリメチルアルミニウムを水素でバブリングしたガ
スを20cc/分、0℃に保持したトリメチルガリウム
を水素でバブリングしたガスを15.0cc/分、水素
ベース10%アルシンを1000cc/分を90分間流
した。まず、上記の成長を圧力10Torrの条件で交
互に5回繰り返して慣らし運転を行った。その後、上記
と同様な条件でエピタキシャル成長を行い、HEMT構
造を作成した。得られたウエハは、液体窒素温度におけ
るシートキャリア濃度が7×1011cm-2、移動度が8
5,000cm2/Vsecであり、ウエハ面内のバラ
ツキは約5%以下と良好な結果を得た。
(Example) Using the vapor phase growth apparatus of FIG. 1 which adopted a growth chamber made of stainless steel, a GaAs layer and Al 0.3 G were formed on a GaAs wafer.
a 0.4 As layer is formed by epitaxial growth and HE
The MT structure was created. A 3-inch GaAs wafer is set in the holder and moved to the vacuum preparation chamber, and the chamber is set to 10 -5 to 1
It was evacuated to 0 -6 Torr. On the other hand, the growth chamber is 10 -8 T
The wafer was evacuated to the orr level, the gate valve was opened, the wafer together with the holder was moved from the vacuum preparation chamber to the growth chamber, and set on the susceptor. Then, cooling water was caused to flow in the cooling water flow path of the growth chamber, the heater was energized to heat the wafer, and the temperature of the wafer was set to 680 ° C. which is the growth temperature. Then, cover the transfer tube and rotate the susceptor at a rotation speed of 15r.
The raw material gas was caused to flow from the top of the growth chamber while rotating at pm for vapor phase growth. The source gas composition was 15.0 cc / min for a gas obtained by bubbling trimethylgallium held at 0 ° C. with hydrogen when the GaAs layer was formed, and the hydrogen base 10
% Arsine was flowed at 1000 cc / min for 100 minutes, and when forming an Al 0.3 Ga 0.7 As layer, a gas obtained by bubbling trimethylaluminum kept at 20 ° C. with hydrogen was added at 20 cc / min, and trimethylgallium kept at 0 ° C. was hydrogenated. The gas bubbled at 15.0 cc / min and the hydrogen-based 10% arsine at 1000 cc / min were flowed for 90 minutes. First, the above-described growth was alternately repeated 5 times under a pressure of 10 Torr to perform a break-in operation. After that, epitaxial growth was performed under the same conditions as described above to form a HEMT structure. The obtained wafer had a sheet carrier concentration of 7 × 10 11 cm -2 and a mobility of 8 at the liquid nitrogen temperature.
The result was 5,000 cm 2 / Vsec, and the variation within the wafer surface was about 5% or less, which is a good result.

その後、80回上記のエピタキシャル成長を繰り返した
が、結晶特性に大きな変動はなく、良質なエピタキシャ
ル層を得た。その際、成長室内壁には反応生成物が相当
付着していたが、ゲートバルブのシート面のリークは認
められず、真空準備室を大気圧に戻した状態で、成長室
内の圧力は6×10-7Torrと真空が保持されてい
た。
After that, the above epitaxial growth was repeated 80 times, but the crystal characteristics did not change significantly, and a high-quality epitaxial layer was obtained. At that time, reaction products were considerably attached to the inner wall of the growth chamber, but no leak was observed on the seat surface of the gate valve, and the pressure in the growth chamber was 6 × with the vacuum preparation chamber returned to atmospheric pressure. A vacuum of 10 −7 Torr was maintained.

(発明の効果) 本発明は、上記構成を採用することにより、金属製の成
長室と真空準備室を用いた気相成長装置において、気密
性の向上により不純物の混入を防ぎ、かつ、成長室内の
円滑なガス流を保証することにより、長期間にわたって
高純度の均質なエピタキシャル層を再現性よく形成する
ことができるようになった。
(Advantageous Effects of the Invention) The present invention, by adopting the above-described configuration, in a vapor phase growth apparatus using a metal growth chamber and a vacuum preparation chamber, prevents the mixing of impurities by improving the airtightness, and By ensuring a smooth gas flow of, it has become possible to form a high-purity homogeneous epitaxial layer with good reproducibility over a long period of time.

【図面の簡単な説明】[Brief description of drawings]

第一図は本発明の一つの具体例である有機金属気相成長
装置の断面図である。 1:搬送装置、2:真空準備室、3:真空排気系、4:
原料ガス供給系、5:扉、6:ゲートバルブ、7:ホル
ダー、8:カセット、9:レール、10:冷却水出口、
11:冷却水入口、12:蓋、13:搬送管、14:真
空排気管、15:成長室、16:サセプタ、17:ウエ
ハ、18:ヒータ、19:ヒータ端子、20:真空排気
系、21:回転機構、22:冷却水流路、23:枝管、
24:冷却水導管、25:ベロー、26:駆動装置
FIG. 1 is a sectional view of a metal-organic vapor phase epitaxy apparatus which is one embodiment of the present invention. 1: Transport device, 2: Vacuum preparation chamber, 3: Vacuum exhaust system, 4:
Raw material gas supply system, 5: door, 6: gate valve, 7: holder, 8: cassette, 9: rail, 10: cooling water outlet,
11: cooling water inlet, 12: lid, 13: transfer pipe, 14: vacuum exhaust pipe, 15: growth chamber, 16: susceptor, 17: wafer, 18: heater, 19: heater terminal, 20: vacuum exhaust system, 21 : Rotating mechanism, 22: cooling water flow path, 23: branch pipe,
24: cooling water conduit, 25: bellows, 26: drive device

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】縦型成長室の中央に半導体ウエハを装着す
る回転式サセプタを配置し、該ウエハ上にエピタキシャ
ル成長を行う有機金属気相成長装置において、ウエハを
予め真空保持する真空準備室を設け、ゲートバルブを有
する搬送管によって真空準備室と成長室を接続し、該搬
送管を介して成長室のサセプタにウエハを搬送する搬送
機構を設け、成長室の搬送用開口部に開閉可能な蓋を設
け、該蓋の内面は成長室内壁と同一材料で構成し、か
つ、蓋の装着時には成長室内壁と連続する滑らかな面を
有し、上記搬送管には蓋を移動して収納するための枝管
を付設し、枝管若しくは搬送管を真空排気系と接続する
ことを特徴とする有機金属気相成長装置。
1. A metal-organic vapor phase epitaxy apparatus in which a rotary susceptor for mounting a semiconductor wafer is arranged in the center of a vertical growth chamber and epitaxial growth is performed on the wafer, and a vacuum preparation chamber for preliminarily holding the wafer in vacuum is provided. , A vacuum preparation chamber and a growth chamber are connected by a transfer pipe having a gate valve, a transfer mechanism for transferring a wafer to the susceptor of the growth chamber is provided through the transfer pipe, and an opening / closing lid is provided at a transfer opening of the growth chamber. The inner surface of the lid is made of the same material as the inner wall of the growth chamber, and has a smooth surface that is continuous with the inner wall of the growth chamber when the lid is attached. A metal-organic vapor phase epitaxy apparatus characterized in that a branch pipe is attached and the branch pipe or the transfer pipe is connected to a vacuum exhaust system.
【請求項2】一端を閉じたベローにより枝管を密封し、
蓋を支持する棒状体をベローの底部に固定して、ベロー
底部を後退することにより蓋を枝管内に収納可能とした
ことを特徴とする特許請求の範囲第一項記載の有機金属
気相成長装置。
2. A branch pipe is sealed with a bellows having one end closed,
The metal-organic vapor phase epitaxy according to claim 1, characterized in that the rod-shaped body supporting the lid is fixed to the bottom portion of the bellows, and the lid can be housed in the branch pipe by retracting the bellows bottom portion. apparatus.
【請求項3】成長室及び蓋を冷却する手段を付設したこ
とを特徴とする特許請求の範囲第一項又は第二項記載の
有機金属気相成長装置。
3. The metal-organic vapor phase epitaxy apparatus according to claim 1 or 2, further comprising means for cooling the growth chamber and the lid.
JP29397687A 1987-11-24 1987-11-24 Metalorganic vapor phase growth equipment Expired - Lifetime JPH0628240B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29397687A JPH0628240B2 (en) 1987-11-24 1987-11-24 Metalorganic vapor phase growth equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29397687A JPH0628240B2 (en) 1987-11-24 1987-11-24 Metalorganic vapor phase growth equipment

Publications (2)

Publication Number Publication Date
JPH01136329A JPH01136329A (en) 1989-05-29
JPH0628240B2 true JPH0628240B2 (en) 1994-04-13

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP29397687A Expired - Lifetime JPH0628240B2 (en) 1987-11-24 1987-11-24 Metalorganic vapor phase growth equipment

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JP (1) JPH0628240B2 (en)

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JPH01136329A (en) 1989-05-29

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